000119722 001__ 119722
000119722 005__ 20250109150035.0
000119722 0247_ $$2doi$$a10.1021/acsami.2c06123
000119722 0248_ $$2sideral$$a129972
000119722 037__ $$aART-2022-129972
000119722 041__ $$aeng
000119722 100__ $$0(orcid)0000-0002-8267-9306$$aTejedor, Inés$$uUniversidad de Zaragoza
000119722 245__ $$aInfluence of the Surface Chemistry of Metal-Organic Polyhedra in Their Assembly into Ultrathin Films for Gas Separation
000119722 260__ $$c2022
000119722 5060_ $$aAccess copy available to the general public$$fUnrestricted
000119722 5203_ $$aThe formation of ultrathin films of Rh-based porous metal-organic polyhedra (Rh-MOPs) by the Langmuir-Blodgett method has been explored. Homogeneous and dense monolayer films were formed at the air-water interface either using two different coordinatively alkyl-functionalized Rh-MOPs (HRhMOP(diz)12 and HRhMOP(oiz)12) or by in situ incorporation of aliphatic chains to the axial sites of dirhodium paddlewheels of another Rh-MOP (OHRhMOP) at the air-liquid interface. All these Rh-MOP monolayers were successively deposited onto different substrates in order to obtain multilayer films with controllable thicknesses. Aliphatic chains were partially removed from HRhMOP(diz)12 films post-synthetically by a simple acid treatment, resulting in a relevant modification of the film hydrophobicity. Moreover, the CO2/N2 separation performance of Rh-MOP-supported membranes was also evaluated, proving that they can be used as selective layers for efficient CO2 separation. © 2022 The Authors. Published by American Chemical Society.
000119722 536__ $$9info:eu-repo/grantAgreement/EC/H2020/654000/EU/World class Science and Innovation with Neutrons in Europe 2020/SINE2020$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 654000-SINE2020$$9info:eu-repo/grantAgreement/ES/MICINN-AEI-FEDER/PID2019-105881RB-I00$$9info:eu-repo/grantAgreement/ES/MCIN/AEI/10.13039/501100011033$$9info:eu-repo/grantAgreement/ES/MINECO/RTI2018-095622-B-100$$9info:eu-repo/grantAgreement/ES/MINECO/SEV-2017-0706
000119722 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000119722 590__ $$a9.5$$b2022
000119722 592__ $$a2.178$$b2022
000119722 591__ $$aNANOSCIENCE & NANOTECHNOLOGY$$b27 / 107 = 0.252$$c2022$$dQ2$$eT1
000119722 593__ $$aMaterials Science (miscellaneous)$$c2022$$dQ1
000119722 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b55 / 343 = 0.16$$c2022$$dQ1$$eT1
000119722 593__ $$aNanoscience and Nanotechnology$$c2022$$dQ1
000119722 593__ $$aMedicine (miscellaneous)$$c2022$$dQ1
000119722 594__ $$a15.7$$b2022
000119722 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000119722 700__ $$0(orcid)0000-0003-3691-3437$$aAndrés, Miguel A.
000119722 700__ $$aCarné-Sánchez, Arnau
000119722 700__ $$aArjona, Mónica
000119722 700__ $$0(orcid)0000-0001-8572-1760$$aPérez-Miana, Marta$$uUniversidad de Zaragoza
000119722 700__ $$0(orcid)0000-0001-6627-0079$$aSánchez-Laínez, Javier
000119722 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, Joaquín$$uUniversidad de Zaragoza
000119722 700__ $$aFontaine, Philippe
000119722 700__ $$aGoldmann, Michel
000119722 700__ $$0(orcid)0000-0003-2095-5843$$aRoubeau, Olivier
000119722 700__ $$aMaspoch, Daniel
000119722 700__ $$0(orcid)0000-0002-3492-6456$$aGascón, Ignacio$$uUniversidad de Zaragoza
000119722 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000119722 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000119722 773__ $$g14 (2022), 27495-27506$$pACS appl. mater. interfaces$$tACS applied materials & interfaces$$x1944-8244
000119722 8564_ $$s11782390$$uhttps://zaguan.unizar.es/record/119722/files/texto_completo.pdf$$yVersión publicada
000119722 8564_ $$s3179956$$uhttps://zaguan.unizar.es/record/119722/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000119722 909CO $$ooai:zaguan.unizar.es:119722$$particulos$$pdriver
000119722 951__ $$a2025-01-09-14:59:05
000119722 980__ $$aARTICLE