000119775 001__ 119775
000119775 005__ 20240731103306.0
000119775 0247_ $$2doi$$a10.1039/c9cc04271g
000119775 0248_ $$2sideral$$a112965
000119775 037__ $$aART-2019-112965
000119775 041__ $$aeng
000119775 100__ $$aLeckie, Dominique
000119775 245__ $$aExploring through-bond and through-space magnetic communication in 1, 3, 2-dithiazolyl radical complexes
000119775 260__ $$c2019
000119775 5060_ $$aAccess copy available to the general public$$fUnrestricted
000119775 5203_ $$aReaction of the methyl-benzodithiazolyl radical (MBDTA) with M(hfac)(2) complexes (M = Mn, Co, Zn) affords the complexes M(hfac)(2)(MBDTA)(2). Strong antiferromagnetic exchange interactions are observed between M(ii) ions and the two S = 1/2 radicals (M = Mn, Co), whereas weak antiferromagnetic interactions are observed between radicals when using the diamagnetic Zn(ii) ion. Strong intermolecular exchange coupling is also evident in Mn(hfac)(2)(MBDTA)(2) and attributed to pi*-pi* contacts between MBDTA radicals which are absent for the Co and Zn derivatives.
000119775 536__ $$9info:eu-repo/grantAgreement/ES/DGA/M4$$9info:eu-repo/grantAgreement/ES/MICINN/PGC2018-099024-B-I00
000119775 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000119775 590__ $$a5.996$$b2019
000119775 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b34 / 176 = 0.193$$c2019$$dQ1$$eT1
000119775 592__ $$a1.992$$b2019
000119775 593__ $$aCatalysis$$c2019$$dQ1
000119775 593__ $$aCeramics and Composites$$c2019$$dQ1
000119775 593__ $$aChemistry (miscellaneous)$$c2019$$dQ1
000119775 593__ $$aSurfaces, Coatings and Films$$c2019$$dQ1
000119775 593__ $$aMaterials Chemistry$$c2019$$dQ1
000119775 593__ $$aMetals and Alloys$$c2019$$dQ1
000119775 593__ $$aElectronic, Optical and Magnetic Materials$$c2019$$dQ1
000119775 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000119775 700__ $$aStephaniuk, Nadia T.
000119775 700__ $$0(orcid)0000-0002-5999-341X$$aArauzo, Ana$$uUniversidad de Zaragoza
000119775 700__ $$0(orcid)0000-0002-3600-1721$$aCampo, Javier$$uUniversidad de Zaragoza
000119775 700__ $$aRawson, Jeremy M.
000119775 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000119775 773__ $$g55, 66 (2019), 9849-9852$$pChem. commun.$$tChemical Communications$$x1359-7345
000119775 8564_ $$s709324$$uhttps://zaguan.unizar.es/record/119775/files/texto_completo.pdf$$yPostprint
000119775 8564_ $$s1958495$$uhttps://zaguan.unizar.es/record/119775/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000119775 909CO $$ooai:zaguan.unizar.es:119775$$particulos$$pdriver
000119775 951__ $$a2024-07-31-09:38:00
000119775 980__ $$aARTICLE