119775 20240731103306.0 doi 10.1039/c9cc04271g sideral 112965 ART-2019-112965 eng Leckie, Dominique Exploring through-bond and through-space magnetic communication in 1, 3, 2-dithiazolyl radical complexes 2019 Access copy available to the general public Unrestricted Reaction of the methyl-benzodithiazolyl radical (MBDTA) with M(hfac)(2) complexes (M = Mn, Co, Zn) affords the complexes M(hfac)(2)(MBDTA)(2). Strong antiferromagnetic exchange interactions are observed between M(ii) ions and the two S = 1/2 radicals (M = Mn, Co), whereas weak antiferromagnetic interactions are observed between radicals when using the diamagnetic Zn(ii) ion. Strong intermolecular exchange coupling is also evident in Mn(hfac)(2)(MBDTA)(2) and attributed to pi*-pi* contacts between MBDTA radicals which are absent for the Co and Zn derivatives. info:eu-repo/grantAgreement/ES/DGA/M4 info:eu-repo/grantAgreement/ES/MICINN/PGC2018-099024-B-I00 info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 5.996 2019 CHEMISTRY, MULTIDISCIPLINARY 34 / 176 = 0.193 2019 Q1 T1 1.992 2019 Catalysis 2019 Q1 Ceramics and Composites 2019 Q1 Chemistry (miscellaneous) 2019 Q1 Surfaces, Coatings and Films 2019 Q1 Materials Chemistry 2019 Q1 Metals and Alloys 2019 Q1 Electronic, Optical and Magnetic Materials 2019 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Stephaniuk, Nadia T. Arauzo, Ana Universidad de Zaragoza (orcid)0000-0002-5999-341X Campo, Javier Universidad de Zaragoza (orcid)0000-0002-3600-1721 Rawson, Jeremy M. 2003 395 Universidad de Zaragoza Dpto. Física Materia Condensa. Área Física Materia Condensada 55, 66 (2019), 9849-9852 Chem. commun. Chemical Communications 1359-7345 709324 http://zaguan.unizar.es/record/119775/files/texto_completo.pdf Postprint 1958495 http://zaguan.unizar.es/record/119775/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:119775 articulos driver 2024-07-31-09:38:00 ARTICLE