000120004 001__ 120004
000120004 005__ 20231129152508.0
000120004 0247_ $$2doi$$a10.1039/d1qi00586c
000120004 0248_ $$2sideral$$a126861
000120004 037__ $$aART-2021-126861
000120004 041__ $$aeng
000120004 100__ $$aBlasco D.
000120004 245__ $$aMultidisciplinary study on the hydrogelation of the digold(i) complex [{Au(9: N -adeninate)}2(µ-dmpe)]: Optical, rheological, and quasi-elastic neutron scattering perspectives
000120004 260__ $$c2021
000120004 5060_ $$aAccess copy available to the general public$$fUnrestricted
000120004 5203_ $$aHerein, the syntheses of [{Au(9N-adeninate)}2(µ-dmpe)] (2, dmpe = 1, 2-bis(dimethylphosphino)ethane) and its chloride precursor [(AuCl)2(µ-dmpe)] (1) are described. X-ray diffraction of 2 reveals a short intramolecular aurophilic interaction (2.9921(7) Å), which is present even when 2 crystallizes from its own hydrometallogel (3.0512(3) Å). This interaction is demonstrated by TD-DFT calculations to be participating in the intense blue phosphorescence that 2 displays in the solid state and, presumably, also in the hydrogel one. Finally, as complex 2 could be understood as a formal dimer of LMWG [Au(9N-adeninate)(PMe3)] (3), the hydrogelation of the former is examined, with special regard to its optical, rheological and quasi-elastic neutron scattering properties, which are compared to those of 3
000120004 536__ $$9info:eu-repo/grantAgreement/ES/MCIU-FEDER/ECQ2018-004082$$9info:eu-repo/grantAgreement/ES/MICINN/PID2019-104379RB-C22
000120004 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000120004 590__ $$a7.779$$b2021
000120004 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b3 / 46 = 0.065$$c2021$$dQ1$$eT1
000120004 592__ $$a1.316$$b2021
000120004 593__ $$aInorganic Chemistry$$c2021$$dQ1
000120004 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000120004 700__ $$aLópez-De-Luzuriaga J.M.
000120004 700__ $$aMonge M.
000120004 700__ $$aOlmos M.E.
000120004 700__ $$aRodríguez-Castillo M.
000120004 700__ $$0(orcid)0000-0003-2212-447X$$aAmaveda H.$$uUniversidad de Zaragoza
000120004 700__ $$0(orcid)0000-0003-4747-7327$$aMora M.$$uUniversidad de Zaragoza
000120004 700__ $$aGarcía Sakai V.
000120004 700__ $$aMartínez-González J.A.
000120004 7102_ $$15001$$2065$$aUniversidad de Zaragoza$$bDpto. Ciencia Tecnol.Mater.Fl.$$cÁrea Cienc.Mater. Ingen.Metal.
000120004 773__ $$g8, 15 (2021), 3707-3715$$pInorg. chem. front$$tInorganic Chemistry Frontiers$$x2052-1545
000120004 8564_ $$s2964473$$uhttps://zaguan.unizar.es/record/120004/files/texto_completo.pdf$$yPostprint
000120004 8564_ $$s2774718$$uhttps://zaguan.unizar.es/record/120004/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000120004 909CO $$ooai:zaguan.unizar.es:120004$$particulos$$pdriver
000120004 951__ $$a2023-11-29-15:05:01
000120004 980__ $$aARTICLE