120018 20240319081003.0 doi 10.1016/j.ijggc.2022.103791 sideral 130823 ART-2022-130823 eng Hasan, Md R. Universidad de Zaragoza Optimization of MIL-178(Fe) and Pebax® 3533 loading in mixed matrix membranes for CO2 capture 2022 Access copy available to the general public Unrestricted Global warming is considered as a consequence of extensive use of fossil fuels. Post combustion CO2 capture is an interesting and alternative solution where mixed matrix membranes (MMMs) can be an exciting candidate. This research focuses on the optimization of MMM composition consisting of Pebax® 3533 as the polymer matrix and porous coordination polymer (PCP) MIL-178(Fe) as a filler for gas separation application. MIL-178(Fe) characterized with SEM, TEM and TGA were applied to compare bare polymer and MMM. Optimum composition of the MMM obtained was 5 wt.% MIL-178(Fe) in Pebax® 3533. Average thickness of the optimized dense MMM was 116 ± 8 µm. Such MMM showed CO2 permeability and CO2/N2 selectivity of 312 ± 5 Barrer and 25.0 ± 0.5, respectively, 12% and 25% improved regarding the bare membrane. Additionally, optimum MMM was applied for CO2/CH4 separation and successfully compared in terms of improved CO2 permeability and CO2/CH4 selectivity. info:eu-repo/grantAgreement/ES/DGA-FSE/T43-20R info:eu-repo/grantAgreement/ES/MINECO-AEI-FEDER/PID2019-104009RB-I00/AEI/10.13039/501100011033 info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 3.9 2022 ENGINEERING, CHEMICAL 53 / 141 = 0.376 2022 Q2 T2 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY 34 / 46 = 0.739 2022 Q3 T3 ENGINEERING, ENVIRONMENTAL 32 / 55 = 0.582 2022 Q3 T2 ENERGY & FUELS 70 / 119 = 0.588 2022 Q3 T2 0.989 2022 Energy (miscellaneous) 2022 Q1 Pollution 2022 Q1 Management, Monitoring, Policy and Law 2022 Q1 Industrial and Manufacturing Engineering 2022 Q1 8.0 2022 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Zhao, H. Steunou, N. Serre, C. Malankowska, M. (orcid)0000-0001-9595-0831 Téllez, C. Universidad de Zaragoza (orcid)0000-0002-4954-1188 Coronas, J. Universidad de Zaragoza (orcid)0000-0003-1512-4500 5005 555 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Ingeniería Química 121 (2022), 103791[7 pp.] International Journal of Greenhouse Gas Control International Journal of Greenhouse Gas Control 1750-5836 2156270 http://zaguan.unizar.es/record/120018/files/texto_completo.pdf Versión publicada 2632118 http://zaguan.unizar.es/record/120018/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:120018 articulos driver 2024-03-18-14:20:39 ARTICLE