000120129 001__ 120129 000120129 005__ 20240319081025.0 000120129 0247_ $$2doi$$a10.3390/molecules27207002 000120129 0248_ $$2sideral$$a130856 000120129 037__ $$aART-2022-130856 000120129 041__ $$aeng 000120129 100__ $$0(orcid)0000-0001-7904-2729$$aAzpíroz, Ramón 000120129 245__ $$aPreparation of mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes 000120129 260__ $$c2022 000120129 5060_ $$aAccess copy available to the general public$$fUnrestricted 000120129 5203_ $$aA series of mixed bis-NHC rhodium(I) complexes of type RhCl(η2-olefin)(NHC)(NHC’) have been synthesized by a stepwise reaction of [Rh(μ-Cl)(η2-olefin)2]2 with two different NHCs (NHC = N-heterocyclic carbene), in which the steric hindrance of both NHC ligands and the η2-olefin is critical. Similarly, new mixed coumarin-functionalized bis-NHC rhodium complexes have been prepared by a reaction of mono NHC complexes of type RhCl(NHC-coumarin)(η2,η2-cod) with the corresponding azolium salt in the presence of an external base. Both synthetic procedures proceed selectively and allow the preparation of mixed bis-NHC rhodium complexes in good yields. 000120129 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E42-20R$$9info:eu-repo/grantAgreement/ES/MICINN/PID2019-103965GB-I00/AEI/10.13039/501100011033 000120129 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/ 000120129 590__ $$a4.6$$b2022 000120129 592__ $$a0.704$$b2022 000120129 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b63 / 178 = 0.354$$c2022$$dQ2$$eT2 000120129 593__ $$aPharmaceutical Science$$c2022$$dQ1 000120129 591__ $$aBIOCHEMISTRY & MOLECULAR BIOLOGY$$b97 / 285 = 0.34$$c2022$$dQ2$$eT2 000120129 593__ $$aChemistry (miscellaneous)$$c2022$$dQ2 000120129 593__ $$aDrug Discovery$$c2022$$dQ2 000120129 593__ $$aPhysical and Theoretical Chemistry$$c2022$$dQ2 000120129 593__ $$aOrganic Chemistry$$c2022$$dQ2 000120129 593__ $$aAnalytical Chemistry$$c2022$$dQ2 000120129 593__ $$aMedicine (miscellaneous)$$c2022$$dQ2 000120129 593__ $$aMolecular Medicine$$c2022$$dQ3 000120129 594__ $$a6.7$$b2022 000120129 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000120129 700__ $$aKaratas, Mert Olgun 000120129 700__ $$0(orcid)0000-0002-1735-6439$$aPassarelli, Vincenzo 000120129 700__ $$aÖzdemir, Ismail 000120129 700__ $$0(orcid)0000-0002-3327-0918$$aPérez-Torrente, Jesús J.$$uUniversidad de Zaragoza 000120129 700__ $$0(orcid)0000-0003-4460-8678$$aCastarlenas, Ricardo 000120129 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica 000120129 773__ $$g27, 20 (2022), 7002 [15 pp.]$$pMolecules (Basel, Online)$$tMolecules$$x1420-3049 000120129 8564_ $$s2015022$$uhttps://zaguan.unizar.es/record/120129/files/texto_completo.pdf$$yVersión publicada 000120129 8564_ $$s2668018$$uhttps://zaguan.unizar.es/record/120129/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000120129 909CO $$ooai:zaguan.unizar.es:120129$$particulos$$pdriver 000120129 951__ $$a2024-03-18-16:40:48 000120129 980__ $$aARTICLE