120129 20240319081025.0 doi 10.3390/molecules27207002 sideral 130856 ART-2022-130856 eng Azpíroz, Ramón (orcid)0000-0001-7904-2729 Preparation of mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes 2022 Access copy available to the general public Unrestricted A series of mixed bis-NHC rhodium(I) complexes of type RhCl(η2-olefin)(NHC)(NHC’) have been synthesized by a stepwise reaction of [Rh(μ-Cl)(η2-olefin)2]2 with two different NHCs (NHC = N-heterocyclic carbene), in which the steric hindrance of both NHC ligands and the η2-olefin is critical. Similarly, new mixed coumarin-functionalized bis-NHC rhodium complexes have been prepared by a reaction of mono NHC complexes of type RhCl(NHC-coumarin)(η2,η2-cod) with the corresponding azolium salt in the presence of an external base. Both synthetic procedures proceed selectively and allow the preparation of mixed bis-NHC rhodium complexes in good yields. info:eu-repo/grantAgreement/ES/DGA-FSE/E42-20R info:eu-repo/grantAgreement/ES/MICINN/PID2019-103965GB-I00/AEI/10.13039/501100011033 info:eu-repo/semantics/openAccess by http://creativecommons.org/licenses/by/3.0/es/ 4.6 2022 CHEMISTRY, MULTIDISCIPLINARY 63 / 178 = 0.354 2022 Q2 T2 BIOCHEMISTRY & MOLECULAR BIOLOGY 97 / 285 = 0.34 2022 Q2 T2 0.704 2022 Pharmaceutical Science 2022 Q1 Chemistry (miscellaneous) 2022 Q2 Drug Discovery 2022 Q2 Physical and Theoretical Chemistry 2022 Q2 Organic Chemistry 2022 Q2 Analytical Chemistry 2022 Q2 Medicine (miscellaneous) 2022 Q2 Molecular Medicine 2022 Q3 6.7 2022 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Karatas, Mert Olgun Passarelli, Vincenzo (orcid)0000-0002-1735-6439 Özdemir, Ismail Pérez-Torrente, Jesús J. Universidad de Zaragoza (orcid)0000-0002-3327-0918 Castarlenas, Ricardo (orcid)0000-0003-4460-8678 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 27, 20 (2022), 7002 [15 pp.] Molecules (Basel, Online) Molecules 1420-3049 2015022 http://zaguan.unizar.es/record/120129/files/texto_completo.pdf Versión publicada 2668018 http://zaguan.unizar.es/record/120129/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:120129 articulos driver 2024-03-18-16:40:48 ARTICLE