000121115 001__ 121115
000121115 005__ 20240319081002.0
000121115 0247_ $$2doi$$a10.1016/j.fuel.2021.122154
000121115 0248_ $$2sideral$$a126688
000121115 037__ $$aART-2022-126688
000121115 041__ $$aeng
000121115 100__ $$0(orcid)0000-0002-4674-3614$$aAlexandrino, K.
000121115 245__ $$aExperimental and simulation study of the high pressure oxidation of dimethyl carbonate
000121115 260__ $$c2022
000121115 5060_ $$aAccess copy available to the general public$$fUnrestricted
000121115 5203_ $$aAn experimental and modeling study of the oxidation at high pressure of dimethyl carbonate (DMC) has been performed in a quartz tubular flow reactor. Experimental and simulated concentrations of DMC, CO, CO2 and H2 have been obtained for different temperatures (500–1073 K), pressures (20, 40, and 60 atm) and stoichiometries (λ = 0.7, 1, and 35). Both pressure and concentration of oxygen are important parameters for conversion of DMC. The simulations have been carried out using a detailed kinetic mechanism previously developed by the research group. In general, the model is able to reproduce the experimental trends of the different concentration profiles, although some discrepancies are observed between experimental and simulation results. The performance of the model was also evaluated through the simulation of literature data of the oxidation of DMC at atmospheric pressure in a flow reactor and of the DMC ignition delay times under low and high pressures. In this sense, this work contributes to the knowledge of the combustion process of DMC, by providing new experimental data on the conversion of DMC at high pressures and using a kinetic model for the interpretation of the results.
000121115 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FEDER/T22-20R$$9info:eu-repo/grantAgreement/ES/MICINN-AEI-FEDER/RTI2018-098856-B-I00$$9info:eu-repo/grantAgreement/ES/MINECO/BES-2013-063049$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-65226
000121115 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000121115 590__ $$a7.4$$b2022
000121115 592__ $$a1.38$$b2022
000121115 591__ $$aENGINEERING, CHEMICAL$$b19 / 141 = 0.135$$c2022$$dQ1$$eT1
000121115 591__ $$aENERGY & FUELS$$b32 / 119 = 0.269$$c2022$$dQ2$$eT1
000121115 593__ $$aChemical Engineering (miscellaneous)$$c2022$$dQ1
000121115 593__ $$aOrganic Chemistry$$c2022$$dQ1
000121115 593__ $$aFuel Technology$$c2022$$dQ1
000121115 593__ $$aEnergy Engineering and Power Technology$$c2022$$dQ1
000121115 594__ $$a12.2$$b2022
000121115 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000121115 700__ $$0(orcid)0000-0001-5426-6486$$aMillera, Á.$$uUniversidad de Zaragoza
000121115 700__ $$0(orcid)0000-0002-5420-0943$$aBilbao, R.$$uUniversidad de Zaragoza
000121115 700__ $$0(orcid)0000-0003-4679-5761$$aAlzueta, M. U.$$uUniversidad de Zaragoza
000121115 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000121115 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Tecnologi. Medio Ambiente
000121115 773__ $$g309 (2022), 122154 [9 pp.]$$pFuel$$tFuel$$x0016-2361
000121115 8564_ $$s532599$$uhttps://zaguan.unizar.es/record/121115/files/texto_completo.pdf$$yPostprint
000121115 8564_ $$s560239$$uhttps://zaguan.unizar.es/record/121115/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000121115 909CO $$ooai:zaguan.unizar.es:121115$$particulos$$pdriver
000121115 951__ $$a2024-03-18-14:14:11
000121115 980__ $$aARTICLE