| Página principal > Artículos > Multifunctional Nanocarriers Based on Chitosan Oligomers and Graphitic Carbon Nitride Assembly > MARC |
000121217 001__ 121217 000121217 005__ 20240319081021.0 000121217 0247_ $$2doi$$a10.3390/ma15248981 000121217 0248_ $$2sideral$$a131528 000121217 037__ $$aART-2022-131528 000121217 041__ $$aeng 000121217 100__ $$aSantiago-Aliste, Alberto 000121217 245__ $$aMultifunctional Nanocarriers Based on Chitosan Oligomers and Graphitic Carbon Nitride Assembly 000121217 260__ $$c2022 000121217 5060_ $$aAccess copy available to the general public$$fUnrestricted 000121217 5203_ $$aIn this study, a graphitic carbon nitride and chitosan oligomers (g-C3N4–COS) nanocarrier assembly, which was obtained by cross-linking with methacrylic anhydride (MA), was synthesized and characterized. Its characterization was carried out using infrared spectroscopy, elemental and thermal analyses, and transmission electron microscopy. The new nanocarriers (NCs), with an average particle size of 85 nm in diameter and a 0.25 dispersity index, showed photocatalytic activity (associated with the g-C3N4 moiety), susceptibility to enzymatic degradation (due to the presence of the COS moiety), and high encapsulation and moderate-high release efficiencies (>95% and >74%, respectively). As a proof of concept, the visible-light-driven photocatalytic activity of the NCs was tested for rhodamine B degradation and the reduction of uranium(VI) to uranium(IV). Regarding the potential of the nanocarriers for the encapsulation and delivery of bioactive products for crop protection, NCs loaded with Rubia tinctorum extracts were investigated in vitro against three Vitis vinifera phytopathogens (viz. Neofusicoccum parvum, Diplodia seriata, and Xylophilus ampelinus), obtaining minimum inhibitory concentration values of 750, 250, and 187.5 µg·mL−1, respectively. Their antifungal activity was further tested in vivo as a pruning wound protection product in young ‘Tempranillo’ grapevine plants that were artificially infected with the two aforementioned species of the family Botryosphaeriaceae, finding a significant reduction of the necrosis lengths in the inner woody tissues. Therefore, g-C3N4-MA-COS NCs may be put forward as a multifunctional platform for environmental and agrochemical delivery applications. 000121217 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/ 000121217 590__ $$a3.4$$b2022 000121217 592__ $$a0.563$$b2022 000121217 591__ $$aMETALLURGY & METALLURGICAL ENGINEERING$$b20 / 79 = 0.253$$c2022$$dQ2$$eT1 000121217 593__ $$aMaterials Science (miscellaneous)$$c2022$$dQ2 000121217 591__ $$aPHYSICS, APPLIED$$b57 / 160 = 0.356$$c2022$$dQ2$$eT2 000121217 593__ $$aCondensed Matter Physics$$c2022$$dQ2 000121217 591__ $$aPHYSICS, CONDENSED MATTER$$b29 / 67 = 0.433$$c2022$$dQ2$$eT2 000121217 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b174 / 343 = 0.507$$c2022$$dQ3$$eT2 000121217 591__ $$aCHEMISTRY, PHYSICAL$$b84 / 161 = 0.522$$c2022$$dQ3$$eT2 000121217 594__ $$a5.2$$b2022 000121217 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000121217 700__ $$aSánchez-Hernández, Eva 000121217 700__ $$aLanga-Lomba, Natalia 000121217 700__ $$aGonzález-García, Vicente 000121217 700__ $$0(orcid)0000-0003-3009-0935$$aCasanova-Gascón, José$$uUniversidad de Zaragoza 000121217 700__ $$aMartín-Gil, Jesús 000121217 700__ $$0(orcid)0000-0003-2713-2786$$aMartín-Ramos, Pablo$$uUniversidad de Zaragoza 000121217 7102_ $$15011$$2500$$aUniversidad de Zaragoza$$bDpto. CC.Agrar.y Medio Natural$$cArea Ingeniería Agroforestal 000121217 7102_ $$15011$$2705$$aUniversidad de Zaragoza$$bDpto. CC.Agrar.y Medio Natural$$cÁrea Producción Vegetal 000121217 773__ $$g15, 24 (2022), 8981 [18 pp.]$$pMaterials (Basel)$$tMaterials$$x1996-1944 000121217 8564_ $$s5263044$$uhttps://zaguan.unizar.es/record/121217/files/texto_completo.pdf$$yVersión publicada 000121217 8564_ $$s2792390$$uhttps://zaguan.unizar.es/record/121217/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000121217 909CO $$ooai:zaguan.unizar.es:121217$$particulos$$pdriver 000121217 951__ $$a2024-03-18-16:10:20 000121217 980__ $$aARTICLE
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