Double-Layered Pebax® 3533/ZIF-8 Membranes with Single-Walled Carbon Nanotube Buckypapers as Support for Gas Separation

Berned-Samatán, Víctor (Universidad de Zaragoza) ; Téllez, Carlos (Universidad de Zaragoza) ; Coronas, Joaquín (Universidad de Zaragoza)

Resumen: Single-walled carbon nanotube buckypapers (SWCNT-bps) coated with a metal–organic framework ZIF-8 layer were used as supports for the preparation of Pebax® 3533 TFC membranes by both phase inversion and spin coating techniques. Upon proper characterization of the materials by X-ray diffraction, IR spectroscopy, thermogravimetry and electron microscopy, the obtained membranes were tested in gas separation experiments with a 15:85 CO2/N2 mixture. These experiments proved that the ZIF-8 layer prevented from the penetration of the polymer selective film into the SWCNT-bp support, giving rise to a highly permeable selective membrane. The optimum membrane was achieved by the spin-coating method, with better permeation results than that prepared by the phase inversion method, obtaining a CO2 permeance of 566 GPU together with a CO2/N2 selectivity of 20.9.

Idioma: Inglés

DOI: 10.3390/membranes13010071

Año: 2023

Publicado en: Membranes 13, 1 (2023), 71 [12 pp.]
ISSN: 2077-0375

Factor impacto JCR: 3.3 (2023)

Categ. JCR: CHEMISTRY, PHYSICAL rank: 82 / 178 = 0.461 (2023) - Q2 - T2
Categ. JCR: POLYMER SCIENCE rank: 36 / 95 = 0.379 (2023) - Q2 - T2
Categ. JCR: MATERIALS SCIENCE, MULTIDISCIPLINARY rank: 196 / 439 = 0.446 (2023) - Q2 - T2
Categ. JCR: ENGINEERING, CHEMICAL rank: 70 / 170 = 0.412 (2023) - Q2 - T2

Factor impacto CITESCORE: 6.1 - Process Chemistry and Technology (Q2) - Chemical Engineering (miscellaneous) (Q2) - Filtration and Separation (Q3)

Factor impacto SCIMAGO: 0.551 - Chemical Engineering (miscellaneous) (Q2) - Process Chemistry and Technology (Q3) - Filtration and Separation (Q3)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FSE/T43-20R
Financiación: info:eu-repo/grantAgreement/ES/MCIN-AEI/PID2019-104009RB-I00-AEI-10.13039-501100011033
Financiación: info:eu-repo/grantAgreement/ES/MICINN/BES-2017-080209

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)