Gold nanoparticle-catalysed functionalization of carbon–hydrogen bonds by carbene transfer reactions

Martínez-Laguna, J. ; Mollar-Cuni, A. ; Ventura-Espinosa, D. ; Martín, S. (Universidad de Zaragoza) ; Caballero, A. ; Mata, J. A. ; Pérez, P. J.

Resumen: Gold nanoparticles stabilized by NHC ligands and supported onto reduced graphene oxide (rGO) catalyse the functionalization of cyclohexane and benzene C–H bonds upon insertion of carbene CHCO2Et (from N2[double bond, length as m-dash]CHCO2Et) groups. This is the first example in which such Csp3-H or Csp2-H bonds are functionalized with this strategy with nanoparticulated gold. This Au-NP@rGO material shows an exceptional activity, providing TON values 5–10 times higher than those already reported for molecular gold catalysts. Recyclability is also effective, reaching an accumulated TON value of 1400 after six consecutive uses.

Idioma: Inglés

DOI: 10.1039/d1dt04351j

Año: 2022

Publicado en: Dalton Transactions 51, 13 (2022), 5250-5256
ISSN: 1477-9226

Factor impacto JCR: 4.0 (2022)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 7 / 42 = 0.167 (2022) - Q1 - T1

Factor impacto CITESCORE: 7.1 - Chemistry (Q1)

Factor impacto SCIMAGO: 0.79 - Inorganic Chemistry (Q1)

Financiación: info:eu-repo/grantAgreement/ES/AEI/PID2020-113797RB-C21
Financiación: info:eu-repo/grantAgreement/ES/DGA/E31-20R
Financiación: info:eu-repo/grantAgreement/ES/MCIU/PID2019-105881RB-I00
Financiación: info:eu-repo/grantAgreement/ES/MICIU/RTI2018-098237-B-C22

Tipo y forma: Artículo (PostPrint)

Área (Departamento): Área Química Física (Dpto. Química Física)