123955 20240319081025.0 doi 10.1039/d1dt04351j sideral 131060 ART-2022-131060 eng Martínez-Laguna, J. Gold nanoparticle-catalysed functionalization of carbon–hydrogen bonds by carbene transfer reactions 2022 Access copy available to the general public Unrestricted Gold nanoparticles stabilized by NHC ligands and supported onto reduced graphene oxide (rGO) catalyse the functionalization of cyclohexane and benzene C–H bonds upon insertion of carbene CHCO2Et (from N2[double bond, length as m-dash]CHCO2Et) groups. This is the first example in which such Csp3-H or Csp2-H bonds are functionalized with this strategy with nanoparticulated gold. This Au-NP@rGO material shows an exceptional activity, providing TON values 5–10 times higher than those already reported for molecular gold catalysts. Recyclability is also effective, reaching an accumulated TON value of 1400 after six consecutive uses. info:eu-repo/grantAgreement/ES/AEI/PID2020-113797RB-C21 info:eu-repo/grantAgreement/ES/DGA/E31-20R info:eu-repo/grantAgreement/ES/MCIU/PID2019-105881RB-I00 info:eu-repo/grantAgreement/ES/MICIU/RTI2018-098237-B-C22 info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 4.0 2022 CHEMISTRY, INORGANIC & NUCLEAR 7 / 42 = 0.167 2022 Q1 T1 0.79 2022 Inorganic Chemistry 2022 Q1 7.1 2022 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Mollar-Cuni, A. Ventura-Espinosa, D. Martín, S. Universidad de Zaragoza (orcid)0000-0001-9193-3874 Caballero, A. Mata, J. A. Pérez, P. J. 2012 755 Universidad de Zaragoza Dpto. Química Física Área Química Física 51, 13 (2022), 5250-5256 Dalton Trans. Dalton Transactions 1477-9226 1218524 http://zaguan.unizar.es/record/123955/files/texto_completo.pdf Postprint 2641817 http://zaguan.unizar.es/record/123955/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:123955 articulos driver 2024-03-18-16:38:34 ARTICLE