000124026 001__ 124026
000124026 005__ 20240731103319.0
000124026 0247_ $$2doi$$a10.1126/science.ade1771
000124026 0248_ $$2sideral$$a132344
000124026 037__ $$aART-2023-132344
000124026 041__ $$aeng
000124026 100__ $$aLi, Jian
000124026 245__ $$aA 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
000124026 260__ $$c2023
000124026 5060_ $$aAccess copy available to the general public$$fUnrestricted
000124026 5203_ $$aZeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cation exchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption and processing of large molecules but challenge our synthetic ability. We report a new, highly stable pure silica zeolite called ZEO-3, which has a multidimensional, interconnected system of extra-large pores open through windows made by 16 and 14 silicate tetrahedra, the least dense polymorph of silica known so far. This zeolite was formed by an unprecedented one-dimensional to three-dimensional (1D-to-3D) topotactic condensation of a chain silicate. With a specific surface area of more than 1000 square meters per gram, ZEO-3 showed a high performance for volatile organic compound abatement and recovery compared with other zeolites and metal-organic frameworks.
000124026 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000124026 590__ $$a44.7$$b2023
000124026 592__ $$a11.902$$b2023
000124026 591__ $$aMULTIDISCIPLINARY SCIENCES$$b3 / 134 = 0.022$$c2023$$dQ1$$eT1
000124026 593__ $$aMultidisciplinary$$c2023$$dQ1
000124026 593__ $$aHistory and Philosophy of Science$$c2023$$dQ1
000124026 594__ $$a61.1$$b2023
000124026 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000124026 700__ $$aGao, Zihao Rei
000124026 700__ $$aLin, Qing-Fang
000124026 700__ $$aLiu, Chenxu
000124026 700__ $$aGao, Fangxin
000124026 700__ $$aLin, Cong
000124026 700__ $$aZhang, Siyao
000124026 700__ $$aDeng, Hua
000124026 700__ $$0(orcid)0000-0002-5229-2717$$aMayoral, Alvaro$$uUniversidad de Zaragoza
000124026 700__ $$aFan, Wei
000124026 700__ $$aLuo, Song
000124026 700__ $$aChen, Xiaobo
000124026 700__ $$aHe, Hong
000124026 700__ $$aCamblor, Miguel A.
000124026 700__ $$aChen, Fei-Jian
000124026 700__ $$aYu, Jihong
000124026 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000124026 773__ $$g379, 6629 (2023), 283-287$$pSci.$$tScience$$x0036-8075
000124026 8564_ $$s1227523$$uhttps://zaguan.unizar.es/record/124026/files/texto_completo.pdf$$yPostprint
000124026 8564_ $$s1812857$$uhttps://zaguan.unizar.es/record/124026/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000124026 909CO $$ooai:zaguan.unizar.es:124026$$particulos$$pdriver
000124026 951__ $$a2024-07-31-09:42:13
000124026 980__ $$aARTICLE