000124380 001__ 124380
000124380 005__ 20240319081029.0
000124380 0247_ $$2doi$$a10.1039/d2sc05105b
000124380 0248_ $$2sideral$$a132737
000124380 037__ $$aART-2022-132737
000124380 041__ $$aeng
000124380 100__ $$0(orcid)0000-0002-5823-0314$$aSoria-Carrera, Héctor
000124380 245__ $$aPolyoxometalate–peptide hybrid materials: from structure–property relationships to applications
000124380 260__ $$c2022
000124380 5060_ $$aAccess copy available to the general public$$fUnrestricted
000124380 5203_ $$aOrgano-functionalisation of polyoxometalates (POMs) represents an effective approach to obtain diverse arrays of functional structures and materials, where the introduction of organic moieties into the POM molecules can dramatically change their surface chemistry, charge, polarity, and redox properties. The synergistic combination of POMs and peptides, which perform a myriad of essential roles within cellular biochemistry, including protection and transport in living organisms, leads to functional hybrid materials with unique properties. In this Perspective article, we present the principal synthetic routes to prepare and characterise POM–peptide hybrids, together with a comprehensive description of how their properties – such as redox chemistry, stereochemistry and supramolecular self-assembly – give rise to materials with relevant catalytic, adhesive, and biomedical applications. By presenting the state-of-the-art of the POM–peptide field, we show specifically how emerging chemical approaches can be harnessed to develop tailored POM–peptide materials with synergistic properties for applications in a variety of disciplines.
000124380 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E15-20R$$9info:eu-repo/grantAgreement/EC/H2020/845427/EU/Peptide-functionalized POMs as biofilm disruption agents: searching for synergy in bactericidal materials/PePiPOM$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 845427-PePiPOM$$9info:eu-repo/grantAgreement/ES/MEC/FPU2016-02456$$9info:eu-repo/grantAgreement/ES/MICINN/PID2019-109333RB-I00
000124380 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000124380 590__ $$a8.4$$b2022
000124380 592__ $$a2.762$$b2022
000124380 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b32 / 178 = 0.18$$c2022$$dQ1$$eT1
000124380 593__ $$aChemistry (miscellaneous)$$c2022$$dQ1
000124380 594__ $$a15.2$$b2022
000124380 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000124380 700__ $$0(orcid)0000-0002-3830-7847$$aAtrián-Blasco, Elena
000124380 700__ $$0(orcid)0000-0003-0702-8260$$aMartín-Rapún, Rafael$$uUniversidad de Zaragoza
000124380 700__ $$0(orcid)0000-0003-4848-414X$$aMitchell, Scott G.
000124380 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000124380 773__ $$g14, 1 (2022), 10-28$$pChem. sci.$$tCHEMICAL SCIENCE$$x2041-6520
000124380 8564_ $$s2834480$$uhttps://zaguan.unizar.es/record/124380/files/texto_completo.pdf$$yVersión publicada
000124380 8564_ $$s1915298$$uhttps://zaguan.unizar.es/record/124380/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000124380 909CO $$ooai:zaguan.unizar.es:124380$$particulos$$pdriver
000124380 951__ $$a2024-03-18-17:03:40
000124380 980__ $$aARTICLE