124380 20240319081029.0 doi 10.1039/d2sc05105b sideral 132737 ART-2022-132737 eng Soria-Carrera, Héctor (orcid)0000-0002-5823-0314 Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications 2022 Access copy available to the general public Unrestricted Organo-functionalisation of polyoxometalates (POMs) represents an effective approach to obtain diverse arrays of functional structures and materials, where the introduction of organic moieties into the POM molecules can dramatically change their surface chemistry, charge, polarity, and redox properties. The synergistic combination of POMs and peptides, which perform a myriad of essential roles within cellular biochemistry, including protection and transport in living organisms, leads to functional hybrid materials with unique properties. In this Perspective article, we present the principal synthetic routes to prepare and characterise POM–peptide hybrids, together with a comprehensive description of how their properties – such as redox chemistry, stereochemistry and supramolecular self-assembly – give rise to materials with relevant catalytic, adhesive, and biomedical applications. By presenting the state-of-the-art of the POM–peptide field, we show specifically how emerging chemical approaches can be harnessed to develop tailored POM–peptide materials with synergistic properties for applications in a variety of disciplines. info:eu-repo/grantAgreement/ES/DGA-FSE/E15-20R info:eu-repo/grantAgreement/EC/H2020/845427/EU/Peptide-functionalized POMs as biofilm disruption agents: searching for synergy in bactericidal materials/PePiPOM This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 845427-PePiPOM info:eu-repo/grantAgreement/ES/MEC/FPU2016-02456 info:eu-repo/grantAgreement/ES/MICINN/PID2019-109333RB-I00 info:eu-repo/semantics/openAccess by http://creativecommons.org/licenses/by/3.0/es/ 8.4 2022 CHEMISTRY, MULTIDISCIPLINARY 32 / 178 = 0.18 2022 Q1 T1 2.762 2022 Chemistry (miscellaneous) 2022 Q1 15.2 2022 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Atrián-Blasco, Elena (orcid)0000-0002-3830-7847 Martín-Rapún, Rafael Universidad de Zaragoza (orcid)0000-0003-0702-8260 Mitchell, Scott G. (orcid)0000-0003-4848-414X 2013 765 Universidad de Zaragoza Dpto. Química Orgánica Área Química Orgánica 14, 1 (2022), 10-28 Chem. sci. CHEMICAL SCIENCE 2041-6520 2834480 http://zaguan.unizar.es/record/124380/files/texto_completo.pdf Versión publicada 1915298 http://zaguan.unizar.es/record/124380/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:124380 articulos driver 2024-03-18-17:03:40 ARTICLE