000125739 001__ 125739
000125739 005__ 20241125101125.0
000125739 0247_ $$2doi$$a10.1002/ejic.202300037
000125739 0248_ $$2sideral$$a133165
000125739 037__ $$aART-2023-133165
000125739 041__ $$aeng
000125739 100__ $$aPécharman, Anne-Frédérique M.
000125739 245__ $$aIsolation of Bis- and Mono-Cyclometallated Ru-IMes complexes upon reaction of [Ru(PPh3)3HCl], IMes and ZnMe2
000125739 260__ $$c2023
000125739 5060_ $$aAccess copy available to the general public$$fUnrestricted
000125739 5203_ $$aAddition of an excess of ZnMe2 to a mixture of [Ru(PPh3)3HCl] and IMes (IMes=1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene) yields the bis-cyclometallated complex, [Ru(IMes)“(PPh3)2] 2, together with the mono-cyclometallated, Ru−Zn heterobimetallic complex [Ru(IMes)′(PPh3)2(ZnMe)] 3. Treatment of 2 with H2, PhSiH3 or pinacolborane yields the previously reported complex, [Ru(IMes)′(PPh3)2H] 1, the synthesis of which has been reinvestigated. Further studies of small molecule reactivity show that 1 adds H2 to give [Ru(IMes)(PPh3)2H4] 4, whilst 2 reacts with catecholborane to give [Ru(IMes-Bcat)′(PPh3)2H] 5, in which (IMes-Bcat)′ signifies a borylated NHC ligand that is singly-metallated onto Ru. Treatment of 2 with CO gives the 18-electron dicarbonyl product [Ru(IMes)”(PPh3)(CO)2] 6. Compounds 1–3, 5 and 6 have been structurally characterised.
000125739 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FEDER/E08-17R$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2017-83421-P
000125739 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000125739 590__ $$a2.2$$b2023
000125739 592__ $$a0.481$$b2023
000125739 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b23 / 44 = 0.523$$c2023$$dQ3$$eT2
000125739 593__ $$aInorganic Chemistry$$c2023$$dQ2
000125739 594__ $$a4.3$$b2023
000125739 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000125739 700__ $$aRoberts, Erika M.
000125739 700__ $$aMiloserdov, Fedor M.
000125739 700__ $$0(orcid)0000-0002-7806-8959$$aVarela-Izquierdo, Victor
000125739 700__ $$aMahon, Mary F.
000125739 700__ $$aWhittlesey, Michael K.
000125739 773__ $$g26, 12 (2023), e202300037 [11 pp.]$$pEur. j. inorg. chem.$$tEuropean Journal of Inorganic Chemistry$$x1434-1948
000125739 8564_ $$s4436202$$uhttps://zaguan.unizar.es/record/125739/files/texto_completo.pdf$$yVersión publicada
000125739 8564_ $$s2848747$$uhttps://zaguan.unizar.es/record/125739/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000125739 909CO $$ooai:zaguan.unizar.es:125739$$particulos$$pdriver
000125739 951__ $$a2024-11-22-11:57:23
000125739 980__ $$aARTICLE