000125758 001__ 125758
000125758 005__ 20241125101133.0
000125758 0247_ $$2doi$$a10.1039/d2ra07929a
000125758 0248_ $$2sideral$$a133387
000125758 037__ $$aART-2023-133387
000125758 041__ $$aeng
000125758 100__ $$0(orcid)0000-0001-9626-3726$$aRaso, Raquel
000125758 245__ $$aAqueous phase hydrogenolysis of glycerol with in situ generated hydrogen over Ni/Al3Fe1 catalyst: effect of the calcination temperature
000125758 260__ $$c2023
000125758 5060_ $$aAccess copy available to the general public$$fUnrestricted
000125758 5203_ $$aThe present work studied the influence of the calcination temperature on the aqueous phase hydrogenolysis of glycerol with in situ generated hydrogen over a Ni/Al3Fe1 catalyst. The Ni/Al3Fe1 catalyst was synthesized by the co-precipitation method at 28 mol% of Ni (Ni/(Ni + Al + Fe)) and a molar ratio of Al/Fe of 3/1. The prepared catalyst was calcined at different temperatures (500–750 °C). The obtained samples were tested for the aqueous phase hydrogenolysis (APH) of glycerol and characterized by several analytical techniques (ICP-OES, H2-TPR, XRD, N2-physisorption, NH3-TPD, STEM, FESEM, and TGA). The catalyst calcined at 625 °C was selected as the best sample due to its high acidity, metal dispersion, and catalytic activity; 1,2-propanediol was the highest carbon selectivity product. In addition, it experienced lower metal leaching than the catalyst calcined at 500 °C
000125758 536__ $$9info:eu-repo/grantAgreement/ES/AEI-FEDER/CTQ2017-86893-R$$9info:eu-repo/grantAgreement/ES/DGA-FEDER/T22-20R$$9info:eu-repo/grantAgreement/ES/MCINN/PID2020-114985RB-I00
000125758 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000125758 590__ $$a3.9$$b2023
000125758 592__ $$a0.715$$b2023
000125758 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b80 / 231 = 0.346$$c2023$$dQ2$$eT2
000125758 593__ $$aChemical Engineering (miscellaneous)$$c2023$$dQ1
000125758 593__ $$aChemistry (miscellaneous)$$c2023$$dQ2
000125758 594__ $$a7.5$$b2023
000125758 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000125758 700__ $$0(orcid)0000-0002-2866-9035$$aLete, Alejandro
000125758 700__ $$0(orcid)0000-0001-7115-9025$$aGarcía, Lucía$$uUniversidad de Zaragoza
000125758 700__ $$0(orcid)0000-0002-2924-3095$$aRuiz, Joaquín$$uUniversidad de Zaragoza
000125758 700__ $$0(orcid)0000-0002-7179-3031$$aOliva, Miriam$$uUniversidad de Zaragoza
000125758 700__ $$0(orcid)0000-0002-5959-3168$$aArauzo, Jesús$$uUniversidad de Zaragoza
000125758 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000125758 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Tecnologi. Medio Ambiente
000125758 773__ $$g13, 8 (2023), 5483-5495$$pRSC ADVANCES$$tRSC Advances$$x2046-2069
000125758 8564_ $$s3296358$$uhttps://zaguan.unizar.es/record/125758/files/texto_completo.pdf$$yVersión publicada
000125758 8564_ $$s2971652$$uhttps://zaguan.unizar.es/record/125758/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000125758 909CO $$ooai:zaguan.unizar.es:125758$$particulos$$pdriver
000125758 951__ $$a2024-11-22-11:59:33
000125758 980__ $$aARTICLE