000125818 001__ 125818 000125818 005__ 20241125101148.0 000125818 0247_ $$2doi$$a10.3390/molecules28062663 000125818 0248_ $$2sideral$$a133365 000125818 037__ $$aART-2023-133365 000125818 041__ $$aeng 000125818 100__ $$aDalmau, David 000125818 245__ $$aLuminescence and Palladium: the Odd couple 000125818 260__ $$c2023 000125818 5060_ $$aAccess copy available to the general public$$fUnrestricted 000125818 5203_ $$aThe synthesis, photophysical properties, and applications of highly fluorescent and phosphorescent palladium complexes are reviewed, covering the period 2018–2022. Despite the fact that the Pd atom appears closely related with an efficient quenching of the fluorescence of different molecules, different synthetic strategies have been recently optimized to achieve the preservation and even the amplification of the luminescent properties of several fluorophores after Pd incorporation. Beyond classical methodologies such as orthopalladation or the use of highly emissive ligands as porphyrins and related systems (for instance, biladiene), new concepts such as AIE (Aggregation Induced Emission) in metallacages or in coordination-driven supramolecular compounds (CDS) by restriction of intramolecular motions (RIM), or complexes showing TADF (Thermally Activated Delayed Fluorescence), are here described and analysed. Without pretending to be comprehensive, selected examples of applications in areas such as the fabrication of lighting devices, biological markers, photodynamic therapy, or oxygen sensing are also here reported. 000125818 536__ $$9info:eu-repo/grantAgreement/ES/AEI/PID2019-106394GB-I00$$9info:eu-repo/grantAgreement/ES/DGA/E19-20R 000125818 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/ 000125818 590__ $$a4.2$$b2023 000125818 592__ $$a0.744$$b2023 000125818 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b77 / 231 = 0.333$$c2023$$dQ2$$eT2 000125818 593__ $$aAnalytical Chemistry$$c2023$$dQ1 000125818 591__ $$aBIOCHEMISTRY & MOLECULAR BIOLOGY$$b88 / 313 = 0.281$$c2023$$dQ2$$eT1 000125818 593__ $$aPharmaceutical Science$$c2023$$dQ1 000125818 593__ $$aChemistry (miscellaneous)$$c2023$$dQ1 000125818 593__ $$aOrganic Chemistry$$c2023$$dQ2 000125818 593__ $$aPhysical and Theoretical Chemistry$$c2023$$dQ2 000125818 593__ $$aDrug Discovery$$c2023$$dQ2 000125818 593__ $$aMedicine (miscellaneous)$$c2023$$dQ2 000125818 593__ $$aMolecular Medicine$$c2023$$dQ3 000125818 594__ $$a7.4$$b2023 000125818 655_4 $$ainfo:eu-repo/semantics/review$$vinfo:eu-repo/semantics/publishedVersion 000125818 700__ $$0(orcid)0000-0001-9779-5820$$aUrriolabeitia, Esteban P. 000125818 773__ $$g28, 6 (2023), 2663 [41 pp.]$$pMolecules (Basel, Online)$$tMolecules$$x1420-3049 000125818 8564_ $$s9909482$$uhttps://zaguan.unizar.es/record/125818/files/texto_completo.pdf$$yVersión publicada 000125818 8564_ $$s2750883$$uhttps://zaguan.unizar.es/record/125818/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000125818 909CO $$ooai:zaguan.unizar.es:125818$$particulos$$pdriver 000125818 951__ $$a2024-11-22-12:05:26 000125818 980__ $$aARTICLE