000126299 001__ 126299
000126299 005__ 20240705134214.0
000126299 0247_ $$2doi$$a10.3390/molecules28072887
000126299 0248_ $$2sideral$$a133605
000126299 037__ $$aART-2023-133605
000126299 041__ $$aeng
000126299 100__ $$aFeringán, Beatriz
000126299 245__ $$aTriphenylamine-containing benzoic acids: synthesis, liquid crystalline and redox properties
000126299 260__ $$c2023
000126299 5060_ $$aAccess copy available to the general public$$fUnrestricted
000126299 5203_ $$aThe synthesis, characterization and liquid crystalline and electrochemical properties of novel triarylamines, in which the triphenylamine platform is non-symmetrically modified with a 4-(6-oxyhexyloxy)benzoic acid group, are reported. Compounds show columnar liquid crystalline behavior, as confirmed through the use of polarized optical microscopy, differential scanning calorimetry and X-ray diffraction. Electrochemical properties were measured using cyclic voltammperometry, obtaining low oxidation potentials and HOMO values that were optimum for consideration as organic semiconductors in hole transport layers. In addition, the photoredox activity of one of these derivatives in dichloromethane was studied under light irradiation. A photooxidation/assembly process under white light irradiation occurs without the assistance of hydrogen bonding amide functional groups.
000126299 536__ $$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/PID2021-122882NB-I00$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-126132NB-I00$$9info:eu-repo/grantAgreement/ES/MICINN-FEDER/PGC2018-093761-B-C31$$9info:eu-repo/grantAgreement/ES/DGA-FSE/E47-20R
000126299 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000126299 592__ $$a0.744$$b2023
000126299 593__ $$aAnalytical Chemistry$$c2023$$dQ1
000126299 593__ $$aPharmaceutical Science$$c2023$$dQ1
000126299 593__ $$aChemistry (miscellaneous)$$c2023$$dQ1
000126299 593__ $$aOrganic Chemistry$$c2023$$dQ2
000126299 593__ $$aPhysical and Theoretical Chemistry$$c2023$$dQ2
000126299 593__ $$aDrug Discovery$$c2023$$dQ2
000126299 593__ $$aMedicine (miscellaneous)$$c2023$$dQ2
000126299 593__ $$aMolecular Medicine$$c2023$$dQ3
000126299 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000126299 700__ $$0(orcid)0000-0003-1807-2072$$aMartínez-Bueno, Alejandro
000126299 700__ $$0(orcid)0000-0001-7091-077X$$aSierra, Teresa
000126299 700__ $$0(orcid)0000-0002-7854-6316$$aGiménez, Raquel
000126299 773__ $$g28, 7 (2023), 2887 [12 pp.]$$pMolecules (Basel, Online)$$tMolecules$$x1420-3049
000126299 8564_ $$s2515627$$uhttps://zaguan.unizar.es/record/126299/files/texto_completo.pdf$$yVersión publicada
000126299 8564_ $$s2710275$$uhttps://zaguan.unizar.es/record/126299/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000126299 909CO $$ooai:zaguan.unizar.es:126299$$particulos$$pdriver
000126299 951__ $$a2024-07-05-12:52:24
000126299 980__ $$aARTICLE