000126401 001__ 126401
000126401 005__ 20241125101131.0
000126401 0247_ $$2doi$$a10.1002/chem.202203907
000126401 0248_ $$2sideral$$a132800
000126401 037__ $$aART-2023-132800
000126401 041__ $$aeng
000126401 100__ $$0(orcid)0000-0003-4789-4649$$aMartínez-Visus, Íñigo$$uUniversidad de Zaragoza
000126401 245__ $$aGreen and fast strategies for energy-efficient preparation of the covalent organic framework TpPa-1
000126401 260__ $$c2023
000126401 5060_ $$aAccess copy available to the general public$$fUnrestricted
000126401 5203_ $$aThree synthesis procedures for the covalent-organic framework (COF) TpPa-1 are studied with the purpose of setting up the most promising one in a fast and green way, leading to a more environmentally friendly and sustainable process. With conventional heating, good crystallinity and a high BET specific surface area (SSA) of up to 1007 m2 ⋅ g−1 are achieved at 170 °C for 3 days using water as the quintessential green solvent. However, the application of microwave radiation in the synthesis for this crystalline porous polymer allows reaction times to be shortened to 30 min while maintaining structural and textural properties (BET SSA of 928 m2 ⋅ g−1) and obtaining yields close to 98 % (vs. 90 % in the hydrothermal synthesis). The water-assisted mechanochemical synthesis is also an environmentally friendly synthetic approach; with heating at 170 °C in a two-step process (10+10 min), high crystallinity is achieved, a BET SSA of 960 m2 ⋅ g−1 and a yield of 98 % for TpPa-1.
000126401 536__ $$9info:eu-repo/grantAgreement/ES/MCIN-AEI/PID2019-104009RB-I00-AEI-10.13039-501100011033$$9info:eu-repo/grantAgreement/ES/MICINN PRE2020-092006
000126401 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000126401 590__ $$a3.9$$b2023
000126401 592__ $$a1.058$$b2023
000126401 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b80 / 231 = 0.346$$c2023$$dQ2$$eT2
000126401 593__ $$aChemistry (miscellaneous)$$c2023$$dQ1
000126401 593__ $$aOrganic Chemistry$$c2023$$dQ1
000126401 593__ $$aCatalysis$$c2023$$dQ2
000126401 594__ $$a7.9$$b2023
000126401 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000126401 700__ $$aUlcuango, Matías
000126401 700__ $$0(orcid)0000-0002-9934-1707$$aZornoza, Beatriz$$uUniversidad de Zaragoza
000126401 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, Joaquín$$uUniversidad de Zaragoza
000126401 700__ $$0(orcid)0000-0002-4954-1188$$aTéllez, Carlos$$uUniversidad de Zaragoza
000126401 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000126401 773__ $$g29, 15 (2023), e202203907 [9 pp.]$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539
000126401 8564_ $$s3131463$$uhttps://zaguan.unizar.es/record/126401/files/texto_completo.pdf$$yVersión publicada
000126401 8564_ $$s2930865$$uhttps://zaguan.unizar.es/record/126401/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000126401 909CO $$ooai:zaguan.unizar.es:126401$$particulos$$pdriver
000126401 951__ $$a2024-11-22-11:59:05
000126401 980__ $$aARTICLE