000126850 001__ 126850 000126850 005__ 20241125101154.0 000126850 0247_ $$2doi$$a10.1016/j.molliq.2023.122019 000126850 0248_ $$2sideral$$a134189 000126850 037__ $$aART-2023-134189 000126850 041__ $$aeng 000126850 100__ $$aHernández-Serrano, V. 000126850 245__ $$apVT behaviour of hydrophilic and hydrophobic eutectic solvents 000126850 260__ $$c2023 000126850 5060_ $$aAccess copy available to the general public$$fUnrestricted 000126850 5203_ $$aAmong the basic principles of green chemistry is the search for less harmful alternative solvents than conventional solvents. Knowing the thermophysical properties of fluids under different pressure and temperature conditions is essential to propose them. Herein, we present data on the densities at several pressures (from 0.1 to 65 MPa) and temperatures (from 283.15 to 338.15 K) of two deep eutectic solvents with hydrophilic characteristics (choline chloride + ethylene glycol or glycerol) and two eutectic solvents with hydrophobic characteristics (camphor + thymol or menthol). We used the Tait equation of state to correlate and calculate derived properties. Moreover, we modelled the mixtures with the PC-SAFT equation of state. The results showed that the hydrophilic solvents were more compact than the hydrophobic ones. The former exhibited an abnormal thermal behaviour of the isobaric thermal expansibility. The deviations in the correlation of densities with the thermodynamic model were between 0.5 and 3%. They were lower for the mixtures with weaker interactions. 000126850 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E31-20R 000126850 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/ 000126850 590__ $$a5.3$$b2023 000126850 592__ $$a0.918$$b2023 000126850 591__ $$aPHYSICS, ATOMIC, MOLECULAR & CHEMICAL$$b6 / 40 = 0.15$$c2023$$dQ1$$eT1 000126850 591__ $$aCHEMISTRY, PHYSICAL$$b58 / 178 = 0.326$$c2023$$dQ2$$eT1 000126850 593__ $$aAtomic and Molecular Physics, and Optics$$c2023$$dQ1 000126850 593__ $$aElectronic, Optical and Magnetic Materials$$c2023$$dQ1 000126850 593__ $$aSpectroscopy$$c2023$$dQ1 000126850 593__ $$aMaterials Chemistry$$c2023$$dQ1 000126850 593__ $$aPhysical and Theoretical Chemistry$$c2023$$dQ1 000126850 593__ $$aCondensed Matter Physics$$c2023$$dQ1 000126850 594__ $$a10.3$$b2023 000126850 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000126850 700__ $$0(orcid)0000-0002-8354-7436$$aMuñoz-Embid, J.$$uUniversidad de Zaragoza 000126850 700__ $$0(orcid)0000-0003-3641-1568$$aBergua, F.$$uUniversidad de Zaragoza 000126850 700__ $$0(orcid)0000-0003-3632-6822$$aLafuente, C.$$uUniversidad de Zaragoza 000126850 700__ $$0(orcid)0000-0003-1810-9488$$aArtal, M.$$uUniversidad de Zaragoza 000126850 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física 000126850 773__ $$g382 (2023), 122019 [11 pp.]$$pJ. mol. liq.$$tJournal of Molecular Liquids$$x0167-7322 000126850 8564_ $$s1446260$$uhttps://zaguan.unizar.es/record/126850/files/texto_completo.pdf$$yVersión publicada 000126850 8564_ $$s2713386$$uhttps://zaguan.unizar.es/record/126850/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000126850 909CO $$ooai:zaguan.unizar.es:126850$$particulos$$pdriver 000126850 951__ $$a2024-11-22-12:08:15 000126850 980__ $$aARTICLE