Resumen: We report on the development of scintillating bolometers based on lithium molybdate crystals that contain molybdenum that has depleted into the double-β active isotope 100Mo (Li2100deplMoO4). We used two Li2100deplMoO4 cubic samples, each of which consisted of 45-millimeter sides and had a mass of 0.28 kg; these samples were produced following the purification and crystallization protocols developed for double-β search experiments with 100Mo-enriched Li2MoO4 crystals. Bolometric Ge detectors were utilized to register the scintillation photons that were emitted by the Li2100deplMoO4 crystal scintillators. The measurements were performed in the CROSS cryogenic set-up at the Canfranc Underground Laboratory (Spain). We observed that the Li2100deplMoO4 scintillating bolometers were characterized by an excellent spectrometric performance (∼3–6 keV of FWHM at 0.24–2.6 MeV γs), moderate scintillation signal (∼0.3–0.6 keV/MeV scintillation-to-heat energy ratio, depending on the light collection conditions), and high radiopurity (228Th and 226Ra activities are below a few µBq/kg), which is comparable with the best reported results of low-temperature detectors that are based on Li2MoO4 using natural or 100Mo-enriched molybdenum content. The prospects of Li2100deplMoO4 bolometers for use in rare-event search experiments are briefly discussed. Idioma: Inglés DOI: 10.3390/s23125465 Año: 2023 Publicado en: Sensors 23, 12 (2023), 5465 [16 pp.] ISSN: 1424-8220 Factor impacto JCR: 3.4 (2023) Categ. JCR: CHEMISTRY, ANALYTICAL rank: 34 / 106 = 0.321 (2023) - Q2 - T1 Categ. JCR: INSTRUMENTS & INSTRUMENTATION rank: 24 / 76 = 0.316 (2023) - Q2 - T1 Categ. JCR: ENGINEERING, ELECTRICAL & ELECTRONIC rank: 122 / 352 = 0.347 (2023) - Q2 - T2 Factor impacto CITESCORE: 7.3 - Atomic and Molecular Physics, and Optics (Q1) - Electrical and Electronic Engineering (Q1) - Analytical Chemistry (Q1) - Information Systems (Q1) - Instrumentation (Q1) - Biochemistry (Q2)