Novel spiro-core dopant-free hole transporting material for planar inverted Perovskite solar cells

Royo, Raquel (Universidad de Zaragoza) ; Sánchez, José G. ; Li, Wenhui ; Martinez-Ferrero, Eugenia ; Palomares, Emilio ; Andreu, Raquel (Universidad de Zaragoza) ; Franco, Santiago (Universidad de Zaragoza)

Resumen: Hole-transporting materials (HTMs) have demonstrated their crucial role in promoting charge extraction, interface recombination, and device stability in perovskite solar cells (PSCs). Herein, we present the synthesis of a novel dopant-free spiro-type fluorine core-based HTM with four ethoxytriisopropylsilane groups (Syl-SC) for inverted planar perovskite solar cells (iPSCs). The thickness of the Syl-SC influences the performance of iPSCs. The best-performing iPSC is achieved with a 0.8 mg/mL Syl-SC solution (ca. 15 nm thick) and exhibits a power conversion efficiency (PCE) of 15.77%, with Jsc = 20.00 mA/cm2, Voc = 1.006 V, and FF = 80.10%. As compared to devices based on PEDOT:PSS, the iPSCs based on Syl-SC exhibit a higher Voc, leading to a higher PCE. Additionally, it has been found that Syl-SC can more effectively suppress charge interfacial recombination in comparison to PEDOT:PSS, which results in an improvement in fill factor. Therefore, Syl-SC, a facilely processed and efficient hole-transporting material, presents a promising cost-effective alternative for inverted perovskite solar cells.

Idioma: Inglés

DOI: 10.3390/nano13142042

Año: 2023

Publicado en: Nanomaterials 13, 14 (2023), 2042 [15 pp.]
ISSN: 2079-4991

Factor impacto JCR: 4.4 (2023)

Categ. JCR: MATERIALS SCIENCE, MULTIDISCIPLINARY rank: 146 / 439 = 0.333 (2023) - Q2 - T2
Categ. JCR: NANOSCIENCE & NANOTECHNOLOGY rank: 62 / 141 = 0.44 (2023) - Q2 - T2
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 70 / 231 = 0.303 (2023) - Q2 - T1
Categ. JCR: PHYSICS, APPLIED rank: 47 / 179 = 0.263 (2023) - Q2 - T1

Factor impacto CITESCORE: 8.5 - Chemical Engineering (all) (Q1) - Materials Science (all) (Q1)

Factor impacto SCIMAGO: 0.798 - Chemical Engineering (miscellaneous) (Q1) - Materials Science (miscellaneous) (Q2)

Financiación: info:eu-repo/grantAgreement/ES/AGAUR/2021 SGR01261
Financiación: info:eu-repo/grantAgreement/ES/DGA/E47-23R
Financiación: info:eu-repo/grantAgreement/ES/DGA-FEDER/E47-20R
Financiación: info:eu-repo/grantAgreement/ES/MICINN/CEX2019-000925-S
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2019-104307GB-I00-AEI-10.13039-501100011033
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2019-109389RB-I00

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Química Orgánica (Dpto. Química Orgánica)