000127074 001__ 127074
000127074 005__ 20240720100836.0
000127074 0247_ $$2doi$$a10.1002/adfm.202307369
000127074 0248_ $$2sideral$$a134484
000127074 037__ $$aART-2023-134484
000127074 041__ $$aeng
000127074 100__ $$aLi, Zhen
000127074 245__ $$aA Metal-Organic Framework Incorporating Eight Different Size Rare-Earth Metal Elements: Toward Multifunctionality À La Carte
000127074 260__ $$c2023
000127074 5060_ $$aAccess copy available to the general public$$fUnrestricted
000127074 5203_ $$aMulti‐metallic multivariate (MTV) rare earth (RE) metal−organic frameworks (MOFs) are of interest for the development of multifunctional materials, however examples with more than three RE cations are rare and obstructed by compositional segregation during synthesis. Herein, this work demonstrates the synthesis of a multi‐metallic MTV RE MOF incorporating two, four, six, or eight different RE ions with different sizes and in nearly equimolar amounts and no compositional segregation. The MOFs are formed by a combination of RE cations (La, Ce, Eu, Gd, Tb, Dy, Y, and Yb) and a 1,7‐di(4‐carboxyphenyl)‐1,7‐dicarba‐closo‐dodecaborane (mCB‐L) linker. The steric bulkiness and acidity of mCB‐L is crucial for the incorporation of different size RE ions into the MOF structure. Demonstration of the incorporation of all RE cations is performed via compositional and structural characterization. The more complex MTV MOF, including all eight RE ions (mCB‐8RE), are also characterized using optical, thermal, and magnetic techniques. Element‐selective X‐ray absorption spectroscopy and X‐ray Magnetic Circular Dichroism measurements allow us to characterize spectroscopically each of the eight RE ions and determine their magnetic moments. This work paves the way for the investigation of MTV MOFs with the possibility to combine RE ions à la carte for diverse applications.
000127074 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E12-23R-RASMIA$$9info:eu-repo/grantAgreement/ES/MINECO/PID2019-106832RB-I00$$9info:eu-repo/grantAgreement/ES/MINECO/PID2021-123287OB-I00$$9info:eu-repo/grantAgreement/ES/MINECO/SEV-2017-0706
000127074 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000127074 590__ $$a18.5$$b2023
000127074 592__ $$a5.496$$b2023
000127074 591__ $$aCHEMISTRY, PHYSICAL$$b11 / 178 = 0.062$$c2023$$dQ1$$eT1
000127074 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b21 / 438 = 0.048$$c2023$$dQ1$$eT1
000127074 591__ $$aNANOSCIENCE & NANOTECHNOLOGY$$b9 / 140 = 0.064$$c2023$$dQ1$$eT1
000127074 591__ $$aPHYSICS, CONDENSED MATTER$$b5 / 79 = 0.063$$c2023$$dQ1$$eT1
000127074 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b10 / 230 = 0.043$$c2023$$dQ1$$eT1
000127074 591__ $$aPHYSICS, APPLIED$$b9 / 179 = 0.05$$c2023$$dQ1$$eT1
000127074 593__ $$aBiomaterials$$c2023$$dQ1
000127074 593__ $$aChemistry (miscellaneous)$$c2023$$dQ1
000127074 593__ $$aCondensed Matter Physics$$c2023$$dQ1
000127074 593__ $$aNanoscience and Nanotechnology$$c2023$$dQ1
000127074 593__ $$aElectronic, Optical and Magnetic Materials$$c2023$$dQ1
000127074 593__ $$aMaterials Science (miscellaneous)$$c2023$$dQ1
000127074 593__ $$aElectrochemistry$$c2023$$dQ1
000127074 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000127074 700__ $$aLi, Xiao-Bao
000127074 700__ $$aLight, Mark E.
000127074 700__ $$aCarrillo, Anna E.
000127074 700__ $$0(orcid)0000-0002-5999-341X$$aArauzo, Ana$$uUniversidad de Zaragoza
000127074 700__ $$aValvidares, Manuel
000127074 700__ $$aRoscini, Claudio
000127074 700__ $$aTeixidor, Francesc
000127074 700__ $$aViñas, Clara
000127074 700__ $$aGándara, Felipe
000127074 700__ $$aBartolomé, Elena
000127074 700__ $$aPlanas, José Giner
000127074 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000127074 773__ $$g33, 47 (2023), 2307369 [15 pp.]$$pAdv. funct. mater.$$tAdvanced Functional Materials$$x1616-301X
000127074 8564_ $$s7949655$$uhttps://zaguan.unizar.es/record/127074/files/texto_completo.pdf$$yVersión publicada
000127074 8564_ $$s2403408$$uhttps://zaguan.unizar.es/record/127074/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000127074 909CO $$ooai:zaguan.unizar.es:127074$$particulos$$pdriver
000127074 951__ $$a2024-07-19-18:44:28
000127074 980__ $$aARTICLE