000127094 001__ 127094
000127094 005__ 20241125101143.0
000127094 0247_ $$2doi$$a10.1021/acs.inorgchem.3c01409
000127094 0248_ $$2sideral$$a134524
000127094 037__ $$aART-2023-134524
000127094 041__ $$aeng
000127094 100__ $$aAlconchel, A.
000127094 245__ $$aThermally activated delayed fluorescence in neutral and cationic copper(I) complexes with the 2-(4-Thiazolyl)benzimidazole ligand
000127094 260__ $$c2023
000127094 5060_ $$aAccess copy available to the general public$$fUnrestricted
000127094 5203_ $$aCationic [Cu(P^P)(Htbz)]PF6 [P^P = xantphos, dpephos; Htbz = 2-(4-thiazolyl)benzimidazole] and the corresponding neutral complexes [Cu(P^P)(tbz)], obtained through deprotonation of the diimine ligand, have been synthesized with the aim of analyzing the role of the diphosphane and Htbz deprotonation in the emissive properties of these complexes. For the study of the diphosphane effect, the luminescence properties of these compounds have been compared with those of the reported analogous derivatives with Htbz and carborane diphosphanes. Complexes [Cu(P^P)(Htbz)]PF6 (P^P = xantphos, dpephos) and [Cu(dpephos)(tbz)] display thermally activated delayed fluorescence, which has been studied, revealing a ΔE(S1–T1) between 658 and 455 cm–1. Theoretical calculations indicate different origins for the absorptions, leading to the observed emissions.
000127094 536__ $$9info:eu-repo/grantAgreement/ES/AEI/PID2019-104379RB-C21$$9info:eu-repo/grantAgreement/ES/DGA/E07-23R$$9info:eu-repo/grantAgreement/ES/MINECO/BES2017-082997
000127094 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000127094 590__ $$a4.3$$b2023
000127094 592__ $$a0.928$$b2023
000127094 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b8 / 44 = 0.182$$c2023$$dQ1$$eT1
000127094 593__ $$aChemistry (miscellaneous)$$c2023$$dQ1
000127094 593__ $$aPhysical and Theoretical Chemistry$$c2023$$dQ1
000127094 593__ $$aInorganic Chemistry$$c2023$$dQ1
000127094 594__ $$a7.6$$b2023
000127094 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000127094 700__ $$0(orcid)0000-0001-9522-5840$$aCrespo, O.$$uUniversidad de Zaragoza
000127094 700__ $$0(orcid)0000-0003-0553-0695$$aGimeno, M. C.
000127094 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000127094 773__ $$g62, 26 (2023), 10431-10439$$pInorg. chem.$$tInorganic Chemistry$$x0020-1669
000127094 8564_ $$s4752942$$uhttps://zaguan.unizar.es/record/127094/files/texto_completo.pdf$$yVersión publicada
000127094 8564_ $$s2712050$$uhttps://zaguan.unizar.es/record/127094/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000127094 909CO $$ooai:zaguan.unizar.es:127094$$particulos$$pdriver
000127094 951__ $$a2024-11-22-12:03:29
000127094 980__ $$aARTICLE