doi:10.1039/c5cc03296bengRubio-Pérez, LauraIglesias, ManuelMunárriz, JulenPolo, VíctorSanz Miguel, Pablo J.Pérez-Torrente, Jesús J.Oro, Luis A.A bimetallic iridium(ii) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1, 3-bis(2, 6-diisopropylphenylimidazol-2-ylidene))ART-2015-90921A new Ir(II) complex [{Ir(l-jCNHC ,g6Dipp-IDipp)(H)}2 ][BF4 ] 2 has been prepared and fully characterised. This complex acts as a catalyst for the hydroalkynylation of imines according to an unprecedented diiridium-mediated mechanism.2015http://zaguan.unizar.es/record/12754510.1039/c5cc03296bhttp://zaguan.unizar.es/record/127545oai:zaguan.unizar.es:127545info:eu-repo/grantAgreement/ES/DGA/E07info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CSD2009-00050info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CTQ2011-27593info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CTQ2012-35665info:eu-repo/grantAgreement/ES/UZ/KFUPMChemical Communications 51, 48 (2015), 9860-9863All rights reservedhttp://www.europeana.eu/rights/rr-f/info:eu-repo/semantics/openAccess