Catalytic applications of zwitterionic transition metal compounds

Puerta-Oteo, Raquel ; Ojeda-Amador, Ana I. ; Jimenez, María Victoria ; Perez-Torrente, Jesús J. (Universidad de Zaragoza)

Resumen: This frontiers article highlights recent developments on the application of transition metal-based zwitterionic complexes in catalysis. Recent applications of selected zwitterionic catalysts in polymerization reactions, including the carbonylative polymerization of cyclic ethers, carbon-carbon coupling reactions, the asymmetric hydrogenation of unfunctionalized olefins, and the hydrofunctionalization of alkenes are reviewed. In addition, advances in the field of hydrogenation/dehydrogenation reactions related to energy applications, including the hydrogenation of CO2 and the dehydrogenation of formic acid and N-heterocycles, the functionalization of CO2 with amines and hydrosilanes, and the valorization of polyfunctional bio-based feedstocks, such as the dehygrogenation of glycerol to lactic acid or the reduction of levulinic acid into gamma-valerolactone, are also described.

Idioma: Inglés

DOI: 10.1039/d1dt03746c

Año: 2022

Publicado en: Dalton Transactions 51, 3 (2022), 817-830
ISSN: 1477-9226

Factor impacto JCR: 4.0 (2022)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 7 / 42 = 0.167 (2022) - Q1 - T1

Factor impacto CITESCORE: 7.1 - Chemistry (Q1)

Factor impacto SCIMAGO: 0.79 - Inorganic Chemistry (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FSE/E42-20R
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2019-103965GB-I00/AEI/10.13039/501100011033

Tipo y forma: Artículo (PostPrint)

Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)