000129889 001__ 129889
000129889 005__ 20241125101135.0
000129889 0247_ $$2doi$$a10.1021/acs.est.3c03686
000129889 0248_ $$2sideral$$a136217
000129889 037__ $$aART-2023-136217
000129889 041__ $$aeng
000129889 100__ $$aSong, Xue-Chao
000129889 245__ $$aApplication of Ion mobility Spectrometry and the derived collision Cross Section in the Analysis of Environmental Organic Micropollutants
000129889 260__ $$c2023
000129889 5060_ $$aAccess copy available to the general public$$fUnrestricted
000129889 5203_ $$aIon mobility spectrometry (IMS) is a rapid gas-phase separation technique, which can distinguish ions on the basis of their size, shape, and charge. The IMS-derived collision cross section (CCS) can serve as additional identification evidence for the screening of environmental organic micropollutants (OMPs). In this work, we summarize the published experimental CCS values of environmental OMPs, introduce the current CCS prediction tools, summarize the use of IMS and CCS in the analysis of environmental OMPs, and finally discussed the benefits of IMS and CCS in environmental analysis. An up-to-date CCS compendium for environmental contaminants was produced by combining CCS databases and data sets of particular types of environmental OMPs, including pesticides, drugs, mycotoxins, steroids, plastic additives, per- and polyfluoroalkyl substances (PFAS), polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs), as well as their well-known transformation products. A total of 9407 experimental CCS values from 4170 OMPs were retrieved from 23 publications, which contain both drift tube CCS in nitrogen (DTCCSN2) and traveling wave CCS in nitrogen (TWCCSN2). A selection of publicly accessible and in-house CCS prediction tools were also investigated; the chemical space covered by the training set and the quality of CCS measurements seem to be vital factors affecting the CCS prediction accuracy. Then, the applications of IMS and the derived CCS in the screening of various OMPs were summarized, and the benefits of IMS and CCS, including increased peak capacity, the elimination of interfering ions, the separation of isomers, and the reduction of false positives and false negatives, were discussed in detail. With the improvement of the resolving power of IMS and enhancements of experimental CCS databases, the practicability of IMS in the analysis of environmental OMPs will continue to improve.
000129889 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/T53-20R$$9info:eu-repo/grantAgreement/ES/MICINN/RTI2018-097805-B-I00
000129889 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000129889 590__ $$a10.9$$b2023
000129889 592__ $$a3.516$$b2023
000129889 591__ $$aENVIRONMENTAL SCIENCES$$b18 / 358 = 0.05$$c2023$$dQ1$$eT1
000129889 591__ $$aENGINEERING, ENVIRONMENTAL$$b7 / 81 = 0.086$$c2023$$dQ1$$eT1
000129889 593__ $$aEnvironmental Chemistry$$c2023$$dQ1
000129889 593__ $$aMedicine (miscellaneous)$$c2023$$dQ1
000129889 593__ $$aChemistry (miscellaneous)$$c2023$$dQ1
000129889 594__ $$a17.5$$b2023
000129889 655_4 $$ainfo:eu-repo/semantics/review$$vinfo:eu-repo/semantics/publishedVersion
000129889 700__ $$0(orcid)0000-0003-2638-9221$$aCanellas, Elena$$uUniversidad de Zaragoza
000129889 700__ $$aDreolin, Nicola
000129889 700__ $$aGoshawk, Jeff
000129889 700__ $$aLv, Meilin
000129889 700__ $$aQu, Guangbo
000129889 700__ $$0(orcid)0000-0003-2685-5739$$aNerin, Cristina$$uUniversidad de Zaragoza
000129889 700__ $$aJiang, Guibin
000129889 7102_ $$12009$$2750$$aUniversidad de Zaragoza$$bDpto. Química Analítica$$cÁrea Química Analítica
000129889 773__ $$g57, 51 (2023), 21485-21502$$pEnviron. sci. technol.$$tENVIRONMENTAL SCIENCE & TECHNOLOGY$$x0013-936X
000129889 8564_ $$s3208943$$uhttps://zaguan.unizar.es/record/129889/files/texto_completo.pdf$$yVersión publicada
000129889 8564_ $$s3003550$$uhttps://zaguan.unizar.es/record/129889/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000129889 909CO $$ooai:zaguan.unizar.es:129889$$particulos$$pdriver
000129889 951__ $$a2024-11-22-12:00:45
000129889 980__ $$aARTICLE