000130304 001__ 130304
000130304 005__ 20240124152850.0
000130304 0247_ $$2doi$$a10.1039/c9dt00703b
000130304 0248_ $$2sideral$$a112494
000130304 037__ $$aART-2019-112494
000130304 041__ $$aeng
000130304 100__ $$0(orcid)0000-0002-0497-1969$$aFernández-Alvarez, Francisco J.$$uUniversidad de Zaragoza
000130304 245__ $$aSynthesis and reactivity at the Ir-MeTpm platform: from k1-N coordination to k3-N-based organometallic chemistry
000130304 260__ $$c2019
000130304 5060_ $$aAccess copy available to the general public$$fUnrestricted
000130304 5203_ $$aReaction of [Ir(µ-Cl)(COE)2]2 (COE = cis-cyclooctene) with tris(3, 5-dimethylpyrazol-1-yl)methane (MeTpm) affords [IrCl(¿1-N-MeTpm)(COD)] (1) (COD = 1, 5-cyclooctadiene). The formation of 1 implies the transfer dehydrogenation of a COE ligand to give COD and COA (cyclooctane). A mechanistic proposal based on DFT calculations that explains this iridium promoted process has been disclosed. Additionally, reactivity studies have allowed the preparation and characterization, including determination of the molecular structures of a number of iridium complexes with the MeTpm ligand in ¿1, ¿2 or ¿3-N coordination modes. Moreover, the first example of an Ir-cyclooctyl complex featuring hydride and carbonyl ligands, whose solid state structure has been determined by X-ray diffraction methods, is reported.
000130304 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E42-17R$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67366-P$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2016-75884-P
000130304 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000130304 590__ $$a4.174$$b2019
000130304 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b5 / 45 = 0.111$$c2019$$dQ1$$eT1
000130304 592__ $$a1.048$$b2019
000130304 593__ $$aInorganic Chemistry$$c2019$$dQ1
000130304 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000130304 700__ $$0(orcid)0000-0001-5823-7965$$aPolo, Víctor$$uUniversidad de Zaragoza
000130304 700__ $$0(orcid)0000-0002-7063-1292$$aGarcía-Orduña, Pilar$$uUniversidad de Zaragoza
000130304 700__ $$0(orcid)0000-0001-8054-2237$$aLahoz, Fernando J.$$uUniversidad de Zaragoza
000130304 700__ $$0(orcid)0000-0002-3327-0918$$aPérez-Torrente, Jesús J.$$uUniversidad de Zaragoza
000130304 700__ $$0(orcid)0000-0001-7154-7239$$aOro, Luis A.$$uUniversidad de Zaragoza
000130304 700__ $$aLalrempuia, Ralte
000130304 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000130304 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000130304 773__ $$g48, 19 (2019), 6455-6463$$pDalton Trans.$$tDalton Transactions$$x1477-9226
000130304 8564_ $$s624304$$uhttps://zaguan.unizar.es/record/130304/files/texto_completo.pdf$$yPostprint
000130304 8564_ $$s2730470$$uhttps://zaguan.unizar.es/record/130304/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000130304 909CO $$ooai:zaguan.unizar.es:130304$$particulos$$pdriver
000130304 951__ $$a2024-01-24-15:01:26
000130304 980__ $$aARTICLE