Homogeneous Catalytic Reduction of CO2 with Silicon-Hydrides, State of the Art

Fernandez-Alvarez, Francisco J. (Universidad de Zaragoza) ; Oro, Luis A. (Universidad de Zaragoza)

Resumen: During recent years, the catalytic transformation of CO2 using silicon-hydrides as reductants has emerged as a promising methodology that allows the selective reduction of CO2 to the formate, formaldehyde, methoxide or methane level under mild reaction conditions. Moreover, some catalysts have been employed for the formylation and/or methylation of the N-H bonds of secondary and/or primary amines by their reaction with CO2 and hydrosilanes. This work summarizes the different catalytic systems that have shown to be efficient for the above-mentioned reactions. Furthermore, a brief description of the reactions performance and the conditions employed in each case is included.

Idioma: Inglés

DOI: 10.1002/cctc.201800699

Año: 2018

Publicado en: ChemCatChem 10, 21 (2018), 4783-4796
ISSN: 1867-3880

Factor impacto JCR: 4.495 (2018)

Categ. JCR: CHEMISTRY, PHYSICAL rank: 43 / 147 = 0.293 (2018) - Q2 - T1

Factor impacto SCIMAGO: 1.472 - Catalysis (Q1) - Physical and Theoretical Chemistry (Q1) - Organic Chemistry (Q1) - Inorganic Chemistry (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FSE/E07
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67366-P

Tipo y forma: Revisión (PostPrint)

Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)