000130601 001__ 130601 000130601 005__ 20240319081016.0 000130601 0247_ $$2doi$$a10.1016/j.carbon.2022.05.051 000130601 0248_ $$2sideral$$a129912 000130601 037__ $$aART-2022-129912 000130601 041__ $$aeng 000130601 100__ $$aCiria-Ramos, Isabel 000130601 245__ $$aFormamidinium halide salts as precursors of carbon nitrides 000130601 260__ $$c2022 000130601 5060_ $$aAccess copy available to the general public$$fUnrestricted 000130601 5203_ $$aPyrolysis of formamidinium halide salts (FAI, FABr) results in a new type of amorphous carbon nitride materials with a mass fraction of 40–50% nitrogen content. Pyrolysis temperature drives final chemical composition, morphology, optical and electrical properties of the material independently of the halide precursor and identifying triazine ring, instead of typical heptazine unit, as the main building block of this material. We elaborated a temperature dependent mechanism of formation for these materials and foresee its potential value as native passivation layer in the field of perovskite solar cells. © 2022 The Authors 000130601 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E13-20R$$9info:eu-repo/grantAgreement/ES/DGA/T03-20R$$9info:eu-repo/grantAgreement/EC/H2020/823717/EU/Enabling Science and Technology through European Electron Microscopy/ESTEEM3$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 823717-ESTEEM3$$9info:eu-repo/grantAgreement/ES/MCIU/RYC-2018-025222-I$$9info:eu-repo/grantAgreement/ES/MICINN AEI/EIN2020-112315$$9info:eu-repo/grantAgreement/ES/MICINN-AEI/PID2019-104272RB-C51/AEI/10.13039/501100011033$$9info:eu-repo/grantAgreement/ES/MICINN-AEI/PID2019-104739GB-I00/AEI-10.13039-501100011033$$9info:eu-repo/grantAgreement/ES/MICINN-AEI/PID2019-107893RB-I00/AEI-10.13039-501100011033$$9info:eu-repo/grantAgreement/ES/MICINN/PID2019-108247RA-I00$$9info:eu-repo/grantAgreement/ES/MINECO-AEI-FEDER/PID2019-104739GB-I00-AEI-10.13039-501100011033 000130601 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/ 000130601 590__ $$a10.9$$b2022 000130601 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b39 / 343 = 0.114$$c2022$$dQ1$$eT1 000130601 591__ $$aCHEMISTRY, PHYSICAL$$b25 / 161 = 0.155$$c2022$$dQ1$$eT1 000130601 592__ $$a2.1$$b2022 000130601 593__ $$aMaterials Science (miscellaneous)$$c2022$$dQ1 000130601 593__ $$aChemistry (miscellaneous)$$c2022$$dQ1 000130601 594__ $$a20.1$$b2022 000130601 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000130601 700__ $$0(orcid)0000-0003-3363-2912$$aNavascués, Nuria 000130601 700__ $$0(orcid)0000-0002-3640-0802$$aDiaw, Fatou 000130601 700__ $$aFurgeaud, Clarisse 000130601 700__ $$0(orcid)0000-0002-2071-9093$$aArenal, Raúl 000130601 700__ $$aAnsón-Casaos, Alejandro 000130601 700__ $$0(orcid)0000-0001-7246-2149$$aHaro, Marta$$uUniversidad de Zaragoza 000130601 700__ $$0(orcid)0000-0001-6040-1920$$aJuarez-Perez, Emilio J. 000130601 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física 000130601 773__ $$g196 (2022), 1035-1046$$pCarbon$$tCarbon$$x0008-6223 000130601 8564_ $$s8834286$$uhttps://zaguan.unizar.es/record/130601/files/texto_completo.pdf$$yVersión publicada 000130601 8564_ $$s2697754$$uhttps://zaguan.unizar.es/record/130601/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000130601 909CO $$ooai:zaguan.unizar.es:130601$$particulos$$pdriver 000130601 951__ $$a2024-03-18-15:37:41 000130601 980__ $$aARTICLE