000130667 001__ 130667
000130667 005__ 20240130150402.0
000130667 0247_ $$2doi$$a10.1021/acsmacrolett.8b00505
000130667 0248_ $$2sideral$$a108100
000130667 037__ $$aART-2018-108100
000130667 041__ $$aeng
000130667 100__ $$0(orcid)0000-0003-1237-6788$$aIguarbe, V.
000130667 245__ $$aMaking Coaxial Wires out of Janus Dendrimers for Efficient Charge Transport
000130667 260__ $$c2018
000130667 5060_ $$aAccess copy available to the general public$$fUnrestricted
000130667 5203_ $$aHighly conductive coaxial supramolecular wires are prepared by using a new family of Janus dendrimers that combines two rigid aromatic parts and two flexible aliphatic parts. The two external regions consist of a promesogenic block based on a third generation Percec-type dendron with four terminal dodecyloxy alkyl chains, whereas the two internal regions are formed by one, two, or three carbazole units bearing flexible spacers. These functional Janus dendrimers self-organize in columnar liquid crystal phases with a strong coaxial segregation within each column. Interestingly, the charge mobility studies revealed that these Janus dendrimers display semiconductor properties with hole mobility values up to 0.5 cm2 V-1 s-1, depending on the packing within the columns which can be tuned by the number of carbazole functional units. The high hole mobility values measured in these materials are among the highest values reported for columnar liquid crystals.
000130667 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-70174
000130667 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000130667 592__ $$a2.201$$b2018
000130667 593__ $$aInorganic Chemistry$$c2018$$dQ1
000130667 593__ $$aPolymers and Plastics$$c2018$$dQ1
000130667 593__ $$aOrganic Chemistry$$c2018$$dQ1
000130667 593__ $$aMaterials Chemistry$$c2018$$dQ1
000130667 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000130667 700__ $$0(orcid)0000-0002-8932-9085$$aConcellón, A.$$uUniversidad de Zaragoza
000130667 700__ $$aTermine, R.
000130667 700__ $$aGolemme, A.
000130667 700__ $$0(orcid)0000-0001-5816-7960$$aBarberá, J.$$uUniversidad de Zaragoza
000130667 700__ $$0(orcid)0000-0001-9866-6633$$aSerrano, J.L.$$uUniversidad de Zaragoza
000130667 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000130667 773__ $$g7, 9 (2018), 1138-1143$$pACS macro lett.$$tACS macro letters$$x2161-1653
000130667 8564_ $$s542073$$uhttps://zaguan.unizar.es/record/130667/files/texto_completo.pdf$$yPostprint
000130667 8564_ $$s2972525$$uhttps://zaguan.unizar.es/record/130667/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000130667 909CO $$ooai:zaguan.unizar.es:130667$$particulos$$pdriver
000130667 951__ $$a2024-01-30-14:06:22
000130667 980__ $$aARTICLE