000130683 001__ 130683
000130683 005__ 20240130150402.0
000130683 0247_ $$2doi$$a10.1039/d0qo00537a
000130683 0248_ $$2sideral$$a119733
000130683 037__ $$aART-2020-119733
000130683 041__ $$aeng
000130683 100__ $$0(orcid)0000-0002-8932-9085$$aConcellon, A.
000130683 245__ $$aSemiconducting and electropolymerizable liquid crystalline carbazole-containing porphyrin-core dendrimers
000130683 260__ $$c2020
000130683 5060_ $$aAccess copy available to the general public$$fUnrestricted
000130683 5203_ $$aThe self-assembly of liquid crystals (LCs) is an important method to control the organization of single molecules into periodically nanostructured phases that have found applications in organic electronics. Herein, we report a new family of LC porphyrin-core dendrimers bearing carbazole moieties at the periphery of the dendrimer. These compounds are synthetic light-harvesting antennas, which exhibit intramolecular energy transfer from the carbazole moieties to the central porphyrin core. We also demonstrate that it is possible to deposit spherical polymeric nanoparticles on ITO electrodesviaelectrochemical crosslinking of peripheral carbazole units. Moreover, the porphyrin-core dendrimers exhibit discotic nematic phases with excellent film-forming properties and a strong tendency towards defect-free homeotropic alignment. Charge mobility studies reveal promising semiconductor properties with high hole mobility values. Therefore, such carbazole-containing LC dendrimers exhibit a unique combination of interesting properties, opening the way for the preparation of new optoelectronic materials.
000130683 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E47-17R$$9info:eu-repo/grantAgreement/ES/MINECO/PGC2018-097583-B-I00
000130683 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000130683 590__ $$a5.281$$b2020
000130683 591__ $$aCHEMISTRY, ORGANIC$$b8 / 57 = 0.14$$c2020$$dQ1$$eT1
000130683 592__ $$a1.377$$b2020
000130683 593__ $$aOrganic Chemistry$$c2020$$dQ1
000130683 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000130683 700__ $$aTermine, R.
000130683 700__ $$aGolemme, A.
000130683 700__ $$0(orcid)0000-0003-1378-0571$$aRomero, P.$$uUniversidad de Zaragoza
000130683 700__ $$0(orcid)0000-0001-7056-3181$$aMarcos, M.
000130683 700__ $$0(orcid)0000-0001-9866-6633$$aSerrano, J.L.$$uUniversidad de Zaragoza
000130683 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000130683 773__ $$g7, 15 (2020), 2008-2015$$pOrganic chemistry frontiers.$$tORGANIC CHEMISTRY FRONTIERS$$x2052-4129
000130683 8564_ $$s763556$$uhttps://zaguan.unizar.es/record/130683/files/texto_completo.pdf$$yPostprint
000130683 8564_ $$s2769366$$uhttps://zaguan.unizar.es/record/130683/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000130683 909CO $$ooai:zaguan.unizar.es:130683$$particulos$$pdriver
000130683 951__ $$a2024-01-30-14:07:31
000130683 980__ $$aARTICLE