130889 20240201151019.0 doi 10.1016/j.molliq.2020.113649 sideral 119114 ART-2020-119114 eng Díaz-Ruiz, Raquel The hydration behavior of D-glucose in the choline chloride: Urea:water mixtures 2020 The hydration behavior of D-glucose in aqueous solutions containing a deep eutectic solvent (DES) was studied in the temperature range: T = (293.15–313.15) K. For that, several volumetric, acoustic and viscometric properties were measured and calculated. The choline chloride + urea (1, 2, molar ratio) eutectic mixture was chosen as co-solvent. The Hepler parameter and the viscosity B-coefficient showed that D-glucose in DES aqueous mixtures is a structure-making agent. Both the molar properties and the transfer properties suggested a strong solute-solvent interaction with predominance of the hydrophilic -hydrophilic contribution. Lastly, the calculated viscous flow activation parameters demonstrated high stability of the hydration structure. Access copy available to the general public Unrestricted info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 6.165 2020 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL 4 / 37 = 0.108 2020 Q1 T1 CHEMISTRY, PHYSICAL 43 / 162 = 0.265 2020 Q2 T1 0.929 2020 Atomic and Molecular Physics, and Optics 2020 Q1 Condensed Matter Physics 2020 Q1 Spectroscopy 2020 Q1 Materials Chemistry 2020 Q1 Physical and Theoretical Chemistry 2020 Q1 Electronic, Optical and Magnetic Materials 2020 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Bergua, Fernando (orcid)0000-0003-3641-1568 Muñoz-Embid, José Universidad de Zaragoza (orcid)0000-0002-8354-7436 Lafuente, Carlos Universidad de Zaragoza (orcid)0000-0003-3632-6822 Artal, Manuela Universidad de Zaragoza (orcid)0000-0003-1810-9488 2012 755 Universidad de Zaragoza Dpto. Química Física Área Química Física 314 (2020), 113649 1-8 J. mol. liq. Journal of Molecular Liquids 0167-7322 419571 http://zaguan.unizar.es/record/130889/files/texto_completo.pdf Postprint 1261548 http://zaguan.unizar.es/record/130889/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:130889 articulos driver 2024-02-01-14:38:22 ARTICLE