000131079 001__ 131079
000131079 005__ 20240205173707.0
000131079 0247_ $$2doi$$a10.1021/acs.inorgchem.0c02238
000131079 0248_ $$2sideral$$a120622
000131079 037__ $$aART-2020-120622
000131079 041__ $$aeng
000131079 100__ $$aCalvo, María
000131079 245__ $$aTunable from Blue to Red Emissive Composites and Solids of Silver Diphosphane Systems with Higher Quantum Yields than the Diphosphane Ligands
000131079 260__ $$c2020
000131079 5060_ $$aAccess copy available to the general public$$fUnrestricted
000131079 5203_ $$aPMMA composites and solids of complexes of formulas [AgX(P–P)]n [n = 1 and 2; X = Cl, NO3, ClO4, CF3COO, and OTf; P–P = dppb, xantphos, (PR2)2C2B10H10 (R = Ph and iPr)] display the whole palette of colors from blue to red upon selection of the anionic ligand (X) and the diphosphane (P–P). The diphosphane seems to play the most important role in tuning the emission energy and thermally activated delayed fluorescence (TADF) behavior. The PMMA composites of the complexes exhibit higher quantum yields than that of the diphosphane ligands and those with dppb are between 28 and 53%. Remarkably, instead of blue-green emissions which dominate the luminescence of silver diphosphane complexes in rigid phases, those with carborane diphosphanes are yellow-orange or orange-red emitters. Theoretical studies have been carried out for complexes with P–P = dppb, X = Cl; P–P = dppic, X = NO3; P–P = dppcc, X = Cl, NO3, and OTf and the mononuclear complexes [AgX(xantphos)] (X = Cl, Br). Optimization of the first excited triplet state was only possible for [AgX(xantphos)] (X = Cl and Br). A mixed MLCT and MC nature could be attributed to the S0 → T1 transition in these three-coordinated complexes.
000131079 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E07-20R$$9info:eu-repo/grantAgreement/ES/MICINN/PID2019-104379RB-C21$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2016-75816-C2-1-P
000131079 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000131079 590__ $$a5.165$$b2020
000131079 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b5 / 45 = 0.111$$c2020$$dQ1$$eT1
000131079 592__ $$a1.348$$b2020
000131079 593__ $$aChemistry (miscellaneous)$$c2020$$dQ1
000131079 593__ $$aPhysical and Theoretical Chemistry$$c2020$$dQ1
000131079 593__ $$aInorganic Chemistry$$c2020$$dQ1
000131079 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000131079 700__ $$0(orcid)0000-0001-9522-5840$$aCrespo, Olga$$uUniversidad de Zaragoza
000131079 700__ $$0(orcid)0000-0003-0553-0695$$aGimeno, M. Concepción$$uUniversidad de Zaragoza
000131079 700__ $$0(orcid)0000-0003-1984-7538$$aLaguna, Antonio$$uUniversidad de Zaragoza
000131079 700__ $$aOliván, M. Teresa
000131079 700__ $$0(orcid)0000-0001-5823-7965$$aPolo, Víctor$$uUniversidad de Zaragoza
000131079 700__ $$aRodríguez, Diego
000131079 700__ $$aSáez-Rocher, José M.
000131079 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000131079 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000131079 773__ $$g59, 19 (2020), 14447-14456$$pInorg. chem.$$tInorganic Chemistry$$x0020-1669
000131079 8564_ $$s1206951$$uhttps://zaguan.unizar.es/record/131079/files/texto_completo.pdf$$yPostprint
000131079 8564_ $$s2602592$$uhttps://zaguan.unizar.es/record/131079/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000131079 909CO $$ooai:zaguan.unizar.es:131079$$particulos$$pdriver
000131079 951__ $$a2024-02-05-15:03:09
000131079 980__ $$aARTICLE