000131086 001__ 131086
000131086 005__ 20240205173707.0
000131086 0247_ $$2doi$$a10.1002/ejic.202100490
000131086 0248_ $$2sideral$$a125790
000131086 037__ $$aART-2021-125790
000131086 041__ $$aeng
000131086 100__ $$aAlconchel, Adrián
000131086 245__ $$aVersatile emissive three-coordinated gold(i) systems-properties and perspectives
000131086 260__ $$c2021
000131086 5060_ $$aAccess copy available to the general public$$fUnrestricted
000131086 5203_ $$aTrigonal planar coordination at gold allows phosphorescent 3MC transitions, not expected for luminescent mononuclear linear gold complexes. The careful selection and nature of the ancillary ligands bonded to gold, being fluorophore groups or not emissive ligands may cause a distortion of ideal trigonal planar coordination favoring different origins for the emissions. Consequently, intraligand (IL) or charge transfer (CT) transitions may be present and besides the expected phosphorescent MC transitions, fluorescence or thermally activated delayed fluorescence (TADF) may be the origin of the luminescence. In addition of the advantages of triplet population and deactivation via phosphorescent or delayed fluorescence processes, these systems are very versatile and may show interesting properties such as mechanochromism and vapochromism and, consequently, have revealed as promising candidates for optical applications. The objective of this review is to provide an overview of the reported luminescent three-coordinated gold systems and to get insight into their emissive properties.
000131086 536__ $$9info:eu-repo/grantAgreement/ES/AEI/PID2019-104379RB-C21$$9info:eu-repo/grantAgreement/ES/DGA-FSE/E07-20R$$9info:eu-repo/grantAgreement/ES/MINECO/BES-2017-082997
000131086 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000131086 590__ $$a2.551$$b2021
000131086 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b23 / 46 = 0.5$$c2021$$dQ2$$eT2
000131086 592__ $$a0.553$$b2021
000131086 593__ $$aInorganic Chemistry$$c2021$$dQ2
000131086 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000131086 700__ $$0(orcid)0000-0001-9522-5840$$aCrespo, Olga$$uUniversidad de Zaragoza
000131086 700__ $$0(orcid)0000-0003-0553-0695$$aGimeno, M. Concepción
000131086 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000131086 773__ $$g2021, 38 (2021), 3913-3925$$pEur. j. inorg. chem.$$tEuropean Journal of Inorganic Chemistry$$x1434-1948
000131086 8564_ $$s773446$$uhttps://zaguan.unizar.es/record/131086/files/texto_completo.pdf$$yPostprint
000131086 8564_ $$s2652610$$uhttps://zaguan.unizar.es/record/131086/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000131086 909CO $$ooai:zaguan.unizar.es:131086$$particulos$$pdriver
000131086 951__ $$a2024-02-05-15:04:11
000131086 980__ $$aARTICLE