000131472 001__ 131472
000131472 005__ 20240731103339.0
000131472 0247_ $$2doi$$a10.1039/d3dt03687a
000131472 0248_ $$2sideral$$a136840
000131472 037__ $$aART-2023-136840
000131472 041__ $$aeng
000131472 100__ $$0(orcid)0000-0002-5298-8351$$aPérez-Sánchez, Juan Carlos
000131472 245__ $$aUnlocking the catalytic potential of gold (II) complexes: a comprehensive reassessment
000131472 260__ $$c2023
000131472 5060_ $$aAccess copy available to the general public$$fUnrestricted
000131472 5203_ $$aGold(II) complexes, unlike their gold(I) and gold(III) counterparts, have been sparsely employed in the field of catalysis. This is primarily due to the challenges associated with isolating and characterising these open-shell species. However, these complexes offer a wide range of possibilities. On one hand, this intermediate oxidation state has proven to be more easily accessible through reduction and oxidation processes compared to the gold(I)/gold(III) redox couple, thereby facilitating potential homo-coupling and cross-coupling reactions. On the other hand, gold(II) exhibits Lewis acid behaviour, bridging the characteristics of the soft acid gold(I) and the hard acid gold(III). In this review, we focus on mono- and dinuclear gold(II) complexes, whether they are isolated and well-studied or proposed as intermediates in cross-coupling reactions induced by the action of oxidants or light. We delve into the unique reactivity and potential applications of these gold(II) species, shedding light on their role in this field. This comprehensive exploration aims to underscore the latent promise of gold(II) complexes in catalysis, offering insights into their structural and mechanistic aspects while highlighting their relevance in contemporary chemical transformations.
000131472 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E07-23R$$9info:eu-repo/grantAgreement/ES/MCIN/AEI/PID2020-117455GB-I00$$9info:eu-repo/grantAgreement/ES/MICINN AEI/PID2022-136861NB-I00$$9info:eu-repo/grantAgreement/ES/MICINN/PID2019-104379RB-C21-AEI-10.13039-501100011033
000131472 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000131472 590__ $$a3.5$$b2023
000131472 592__ $$a0.697$$b2023
000131472 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b13 / 44 = 0.295$$c2023$$dQ2$$eT1
000131472 593__ $$aInorganic Chemistry$$c2023$$dQ1
000131472 594__ $$a6.6$$b2023
000131472 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000131472 700__ $$0(orcid)0000-0002-5244-9569$$aPérez Herrera, Raquel
000131472 700__ $$0(orcid)0000-0003-0553-0695$$aGimeno, M. Concepción
000131472 773__ $$g53, 2 (2023), 382-393$$pDalton Trans.$$tDalton Transactions$$x1477-9226
000131472 8564_ $$s1822931$$uhttps://zaguan.unizar.es/record/131472/files/texto_completo.pdf$$yVersión publicada
000131472 8564_ $$s2792739$$uhttps://zaguan.unizar.es/record/131472/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000131472 909CO $$ooai:zaguan.unizar.es:131472$$particulos$$pdriver
000131472 951__ $$a2024-07-31-09:49:18
000131472 980__ $$aARTICLE