000131567 001__ 131567
000131567 005__ 20240319081005.0
000131567 0247_ $$2doi$$a10.1002/anie.202206831
000131567 0248_ $$2sideral$$a129510
000131567 037__ $$aART-2022-129510
000131567 041__ $$aeng
000131567 100__ $$aHidalgo, Nereida
000131567 245__ $$aEnhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study
000131567 260__ $$c2022
000131567 5060_ $$aAccess copy available to the general public$$fUnrestricted
000131567 5203_ $$aThe organometallic chemistry of 4d and 5d transition metals has been vastly dominated by closed-shell states. The reactivity of their metalloradical species is though remarkable, albeit yet poorly understood and with limited mechanistic investigations available. In this work we report the synthesis and characterization of two mononuclear IrII species, including the first dinitrogen adduct. These compounds activate dihydrogen at a dissimilar rate, in the latter case several orders of magnitude faster than its IrI precursor. A combined experimental/computational investigation to ascertain the mechanism of this transformation in IrII compounds is reported.
000131567 536__ $$9info:eu-repo/grantAgreement/EC/H2020/756575/EU/Cooperative Catalysis: Using Interdisciplinary Chemical Systems to Develop New Cooperative Catalysts/CoopCat$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 756575-CoopCat$$9info:eu-repo/grantAgreement/ES/MCIU/PID2019-110856GA-I00
000131567 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000131567 590__ $$a16.6$$b2022
000131567 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b13 / 178 = 0.073$$c2022$$dQ1$$eT1
000131567 592__ $$a5.573$$b2022
000131567 593__ $$aChemistry (miscellaneous)$$c2022$$dQ1
000131567 593__ $$aCatalysis$$c2022$$dQ1
000131567 594__ $$a26.3$$b2022
000131567 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000131567 700__ $$aMoreno, Juan José
000131567 700__ $$0(orcid)0000-0002-1827-1250$$aGarcía-Rubio, Inés$$uUniversidad de Zaragoza
000131567 700__ $$aCampos, Jesús
000131567 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000131567 773__ $$g61, 35 (2022), e202206831 [7 pp.]$$pAngew. Chem. (Int. ed.)$$tANGEWANDTE CHEMIE-INTERNATIONAL EDITION$$x1433-7851
000131567 8564_ $$s2169913$$uhttps://zaguan.unizar.es/record/131567/files/texto_completo.pdf$$yVersión publicada
000131567 8564_ $$s3027336$$uhttps://zaguan.unizar.es/record/131567/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000131567 909CO $$ooai:zaguan.unizar.es:131567$$particulos$$pdriver
000131567 951__ $$a2024-03-18-14:31:06
000131567 980__ $$aARTICLE