000131789 001__ 131789 000131789 005__ 20241125101141.0 000131789 0247_ $$2doi$$a10.1038/s41467-023-41936-w 000131789 0248_ $$2sideral$$a137126 000131789 037__ $$aART-2023-137126 000131789 041__ $$aeng 000131789 100__ $$aTatay, Sergio 000131789 245__ $$aSynthetic control of correlated disorder in UiO-66 frameworks 000131789 260__ $$c2023 000131789 5060_ $$aAccess copy available to the general public$$fUnrestricted 000131789 5203_ $$aChanging the perception of defects as imperfections in crystalline frameworks into correlated domains amenable to chemical control and targeted design might offer opportunities for the design of porous materials with superior performance or distinctive behavior in catalysis, separation, storage, or guest recognition. From a chemical standpoint, the establishment of synthetic protocols adapted to control the generation and growth of correlated disorder is crucial to consider defect engineering a practicable route towards adjusting framework function. By using UiO-66 as experimental platform, we systematically explored the framework chemical space of the corresponding defective materials. Periodic disorder arising from controlled generation and growth of missing cluster vacancies can be chemically controlled by the relative concentration of linker and modulator, which has been used to isolate a crystallographically pure “disordered” reo phase. Cs-corrected scanning transmission electron microscopy is used to proof the coexistence of correlated domains of missing linker and cluster vacancies, whose relative sizes are fixed by the linker concentration. The relative distribution of correlated disorder in the porosity and catalytic activity of the material reveals that, contrarily to the common belief, surpassing a certain defect concentration threshold can have a detrimental effect. 000131789 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/ 000131789 590__ $$a14.7$$b2023 000131789 592__ $$a4.887$$b2023 000131789 591__ $$aMULTIDISCIPLINARY SCIENCES$$b8 / 134 = 0.06$$c2023$$dQ1$$eT1 000131789 593__ $$aBiochemistry, Genetics and Molecular Biology (miscellaneous)$$c2023$$dQ1 000131789 593__ $$aPhysics and Astronomy (miscellaneous)$$c2023$$dQ1 000131789 593__ $$aChemistry (miscellaneous)$$c2023$$dQ1 000131789 594__ $$a24.9$$b2023 000131789 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000131789 700__ $$aMartínez-Giménez, Sonia 000131789 700__ $$aRubio-Gaspar, Ana 000131789 700__ $$aGómez-Oliveira, Eloy 000131789 700__ $$aCastells-Gil, Javier 000131789 700__ $$aDong, Zhuoya 000131789 700__ $$0(orcid)0000-0002-5229-2717$$aMayoral, Álvaro$$uUniversidad de Zaragoza 000131789 700__ $$aAlmora-Barrios, Neyvis 000131789 700__ $$aM. Padial, Natalia 000131789 700__ $$aMartí-Gastaldo, Carlos 000131789 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada 000131789 773__ $$g14, 1 (2023), [12 pp.]$$tNature communications$$x2041-1723 000131789 787__ $$tSynthetic control of correlated disorder in UiO-66 frameworks$$tSynthetic control of correlated disorder in UiO-66 frameworks$$w10.5281/zenodo.8282712$$whttps://www.ccdc.cam.ac.uk/structures/ 000131789 8564_ $$s2332044$$uhttps://zaguan.unizar.es/record/131789/files/texto_completo.pdf$$yVersión publicada 000131789 8564_ $$s2521385$$uhttps://zaguan.unizar.es/record/131789/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000131789 909CO $$ooai:zaguan.unizar.es:131789$$particulos$$pdriver 000131789 951__ $$a2024-11-22-12:02:32 000131789 980__ $$aARTICLE