000132054 001__ 132054
000132054 005__ 20240301161205.0
000132054 0247_ $$2doi$$a10.1021/ef501313x
000132054 0248_ $$2sideral$$a93384
000132054 037__ $$aART-2014-93384
000132054 041__ $$aeng
000132054 100__ $$0(orcid)0000-0002-7767-3057$$aMarrodan, Lorena
000132054 245__ $$aHigh-pressure study of methyl formate oxidation and its interaction with NO
000132054 260__ $$c2014
000132054 5060_ $$aAccess copy available to the general public$$fUnrestricted
000132054 5203_ $$aAn experimental and modeling study of the influence of pressure on the oxidation of methyl formate (MF) has been performed in the 1-60 bar pressure range, in an isothermal tubular quartz flow reactor in the 573-1073 K temperature range. The influence of stoichiometry, temperature, pressure, and presence of NO on the conversion of MF and the formation of the main products (CH2O, CO2, CO, CH4, and H2) has been analyzed. A detailed kinetic mechanism has been used to interpret the experimental results. The results show that the oxidation regime of MF differs significantly from atmospheric to high-pressure conditions. The impact of the NO presence has been considered, and results indicate that no net reduction of NOx is achieved, even though, at high pressure, the NO-NO2 interconversion results in a slightly increased reactivity of MF.
000132054 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2012-34423
000132054 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000132054 590__ $$a2.79$$b2014
000132054 591__ $$aENGINEERING, CHEMICAL$$b21 / 135 = 0.156$$c2014$$dQ1$$eT1
000132054 591__ $$aENERGY & FUELS$$b32 / 89 = 0.36$$c2014$$dQ2$$eT2
000132054 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000132054 700__ $$0(orcid)0000-0001-5426-6486$$aMillera, Ángela$$uUniversidad de Zaragoza
000132054 700__ $$0(orcid)0000-0002-5420-0943$$aBilbao, Rafael$$uUniversidad de Zaragoza
000132054 700__ $$0(orcid)0000-0003-4679-5761$$aAlzueta, María U.$$uUniversidad de Zaragoza
000132054 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000132054 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Tecnologi. Medio Ambiente
000132054 773__ $$g28, 9 (2014), 6107-6115$$pEnergy fuels$$tEnergy and Fuels$$x0887-0624
000132054 8564_ $$s519924$$uhttps://zaguan.unizar.es/record/132054/files/texto_completo.pdf$$yPostprint
000132054 8564_ $$s1187041$$uhttps://zaguan.unizar.es/record/132054/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000132054 909CO $$ooai:zaguan.unizar.es:132054$$particulos$$pdriver
000132054 951__ $$a2024-03-01-14:35:55
000132054 980__ $$aARTICLE