132054 20240301161205.0 doi 10.1021/ef501313x sideral 93384 ART-2014-93384 eng Marrodan, Lorena (orcid)0000-0002-7767-3057 High-pressure study of methyl formate oxidation and its interaction with NO 2014 An experimental and modeling study of the influence of pressure on the oxidation of methyl formate (MF) has been performed in the 1-60 bar pressure range, in an isothermal tubular quartz flow reactor in the 573-1073 K temperature range. The influence of stoichiometry, temperature, pressure, and presence of NO on the conversion of MF and the formation of the main products (CH2O, CO2, CO, CH4, and H2) has been analyzed. A detailed kinetic mechanism has been used to interpret the experimental results. The results show that the oxidation regime of MF differs significantly from atmospheric to high-pressure conditions. The impact of the NO presence has been considered, and results indicate that no net reduction of NOx is achieved, even though, at high pressure, the NO-NO2 interconversion results in a slightly increased reactivity of MF. Access copy available to the general public Unrestricted info:eu-repo/grantAgreement/ES/MINECO/CTQ2012-34423 info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 2.79 2014 ENGINEERING, CHEMICAL 21 / 135 = 0.156 2014 Q1 T1 ENERGY & FUELS 32 / 89 = 0.36 2014 Q2 T2 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Millera, Ángela Universidad de Zaragoza (orcid)0000-0001-5426-6486 Bilbao, Rafael Universidad de Zaragoza (orcid)0000-0002-5420-0943 Alzueta, María U. Universidad de Zaragoza (orcid)0000-0003-4679-5761 5005 555 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Ingeniería Química 5005 790 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Tecnologi. Medio Ambiente 28, 9 (2014), 6107-6115 Energy fuels Energy and Fuels 0887-0624 519924 http://zaguan.unizar.es/record/132054/files/texto_completo.pdf Postprint 1187041 http://zaguan.unizar.es/record/132054/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:132054 articulos driver 2024-03-01-14:35:55 ARTICLE