132079 20240301161205.0 doi 10.1039/d0cc03217d sideral 118515 ART-2020-118515 eng Abranches, Dinis O. Unveiling the mechanism of hydrotropy: evidence for water-mediated aggregation of hydrotropes around the solute 2020 A recent proposal attributes the origin of hydrotropy to the water-mediated aggregation of hydrotrope molecules around the solute. Experimental evidence for this phenomenon is reported for the first time in this work, using 1H-NMR. A new computational technique to quantify apolarity is introduced and is used to show that apolarity of both solute and hydrotrope is the driving force of hydrotropy. Access copy available to the general public Unrestricted info:eu-repo/grantAgreement/ES/DGA/E37-17R info:eu-repo/grantAgreement/ES/MCIU/RTI2018-093431-B-I00 info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 6.222 2020 CHEMISTRY, MULTIDISCIPLINARY 44 / 178 = 0.247 2020 Q1 T1 1.837 2020 Catalysis 2020 Q1 Ceramics and Composites 2020 Q1 Chemistry (miscellaneous) 2020 Q1 Surfaces, Coatings and Films 2020 Q1 Materials Chemistry 2020 Q1 Metals and Alloys 2020 Q1 Electronic, Optical and Magnetic Materials 2020 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Benfica, Jordana Soares, Bruna P. Leal-Duaso, Alejandro Universidad de Zaragoza (orcid)0000-0002-3256-2089 Sintra, Tania E. Pires Ezquerra, María Elisabet Universidad de Zaragoza (orcid)0000-0002-2676-8814 Shimizu, Seishi Coutinho, Joao A. P. 2013 765 Universidad de Zaragoza Dpto. Química Orgánica Área Química Orgánica 56, 52 (2020), 7143-7146 Chem. commun. Chemical Communications 1359-7345 270094 http://zaguan.unizar.es/record/132079/files/texto_completo.pdf Postprint 2768595 http://zaguan.unizar.es/record/132079/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:132079 articulos driver 2024-03-01-14:38:00 ARTICLE