000132087 001__ 132087
000132087 005__ 20240301161205.0
000132087 0247_ $$2doi$$a10.1021/acssuschemeng.1c01694
000132087 0248_ $$2sideral$$a125015
000132087 037__ $$aART-2021-125015
000132087 041__ $$aeng
000132087 100__ $$0(orcid)0000-0002-3256-2089$$aLeal-Duaso, Alejandro
000132087 245__ $$aDesign of glycerol-based solvents for the immobilization of palladium nanocatalysts: a hydrogenation study
000132087 260__ $$c2021
000132087 5060_ $$aAccess copy available to the general public$$fUnrestricted
000132087 5203_ $$aTwenty-one green solvents, including glycerol-derived ethers, and their eutectic mixtures with two renewable ammonium salts, were used for the straightforward synthesis, stabilization, and immobilization of palladium nanoparticles (Pd NPs). The nature of the solvent allows tuning of the characteristics and properties of resulting catalytic systems in terms of particle size and morphology, stability, reactivity, and recoverability. Pd NPs immobilized in glycerol-based solvents were applied in the catalytic hydrogenation of alkenes, alkynes, and carbonyl compounds, as well as in the selective semihydrogenation of alkynes to alkenes. The optimal experimental parameters and the influence on the reactivity of the physicochemical properties of solvent, mainly the viscosity, were studied. Moreover, the most active and recoverable catalytic system, Pd NPs/N00Cl-100, was fully characterized both in the liquid phase and in the solid state, and its deactivation upon recovery was analyzed.
000132087 536__ $$9info:eu-repo/grantAgreement/ES/DGA-ERDF/E37-20R$$9info:eu-repo/grantAgreement/ES/MEC/FPU14-04338$$9info:eu-repo/grantAgreement/ES/MCIU/RTI2018-093431-B-I00
000132087 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000132087 590__ $$a9.224$$b2021
000132087 591__ $$aENGINEERING, CHEMICAL$$b13 / 142 = 0.092$$c2021$$dQ1$$eT1
000132087 591__ $$aGREEN & SUSTAINABLE SCIENCE & TECHNOLOGY$$b10 / 47 = 0.213$$c2021$$dQ1$$eT1
000132087 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b29 / 179 = 0.162$$c2021$$dQ1$$eT1
000132087 592__ $$a1.743$$b2021
000132087 593__ $$aChemical Engineering (miscellaneous)$$c2021$$dQ1
000132087 593__ $$aRenewable Energy, Sustainability and the Environment$$c2021$$dQ1
000132087 593__ $$aChemistry (miscellaneous)$$c2021$$dQ1
000132087 594__ $$a14.5$$b2021
000132087 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000132087 700__ $$aFavier, Isabelle
000132087 700__ $$aPla, Daniel
000132087 700__ $$0(orcid)0000-0002-2676-8814$$aPires, Elísabet$$uUniversidad de Zaragoza
000132087 700__ $$aGómez, Montserrat
000132087 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000132087 773__ $$g9, 19 (2021), 6875-6885$$pACS sustain. chem. & eng.$$tACS Sustainable Chemistry and Engineering$$x2168-0485
000132087 8564_ $$s6367639$$uhttps://zaguan.unizar.es/record/132087/files/texto_completo.pdf$$yVersión publicada
000132087 8564_ $$s3289638$$uhttps://zaguan.unizar.es/record/132087/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000132087 909CO $$ooai:zaguan.unizar.es:132087$$particulos$$pdriver
000132087 951__ $$a2024-03-01-14:40:40
000132087 980__ $$aARTICLE