132100 20240319080959.0 doi 10.1016/j.cogsc.2022.100610 sideral 128745 ART-2022-128745 eng Gracia-Barberán, S. Are deep eutectic solvents a real alternative to ionic liquids in metal-catalysed reactions? 2022 Access copy available to the general public Unrestricted This microreview tries to answer the question: Are Deep Eutectic Solvents a real alternative to Ionic Liquids in metal-catalysed reactions? We have gathered the outstanding results of the use of DES in metal-catalysed processes and we have compared them to the ones with ILs. The huge possibilities of combinations of the components of the DES provide a vast number of different solvents with tunable properties. These DES have been successfully applied to different reactions such as, couplings or hydrogenations, among others. But additional work is still be necessary to explore the use of DES in other reactions and to go in depth in the study of the influence of the nature of the DES. Finally, we also present the rise in a new family of solvents, bio-based ionic liquids, complementary to the use of DES in order to fully substitute traditional ILs. info:eu-repo/grantAgreement/ES/DGA-ERDF/E37-20R info:eu-repo/grantAgreement/ES/MCIU/RTI2018-093431-B-I00 info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 9.3 2022 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY 11 / 46 = 0.239 2022 Q1 T1 CHEMISTRY, MULTIDISCIPLINARY 26 / 178 = 0.146 2022 Q1 T1 1.478 2022 Catalysis 2022 Q1 Chemistry (miscellaneous) 2022 Q1 Waste Management and Disposal 2022 Q1 Process Chemistry and Technology 2022 Q1 Management, Monitoring, Policy and Law 2022 Q1 13.2 2022 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Leal-Duaso, A. Universidad de Zaragoza (orcid)0000-0002-3256-2089 Pires, E. Universidad de Zaragoza (orcid)0000-0002-2676-8814 2013 765 Universidad de Zaragoza Dpto. Química Orgánica Área Química Orgánica 35 (2022), 100610 [9 pp.] Current Opinion in Green and Sustainable Chemistry 2452-2236 820184 http://zaguan.unizar.es/record/132100/files/texto_completo.pdf Postprint 2257969 http://zaguan.unizar.es/record/132100/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:132100 articulos driver 2024-03-18-13:58:06 ARTICLE