000132108 001__ 132108
000132108 005__ 20240301161205.0
000132108 0247_ $$2doi$$a10.1021/acs.langmuir.1c00904
000132108 0248_ $$2sideral$$a131574
000132108 037__ $$aART-2021-131574
000132108 041__ $$aeng
000132108 100__ $$aNgo, Quynh P.
000132108 245__ $$aReconfigurable pickering emulsions with functionalized carbon nanotubes
000132108 260__ $$c2021
000132108 5060_ $$aAccess copy available to the general public$$fUnrestricted
000132108 5203_ $$aPickering emulsions (PEs) achieve interfacial stabilization by colloidal particle surfactants and are commonly used in food, cosmetics, and pharmaceuticals. Carbon nanotubes (CNTs) have recently been used as stabilizing materials to create dynamic single emulsions. In this study, we used the formation of Meisenheimer complexes on functionalized CNTs to fabricate complex biphasic emulsions containing hydrocarbons (HCs) and fluorocarbons (FCs). The reversible nature of Meisenheimer complex formation allows for further functionalization at the droplet–water interface. The strong affinity of fluorofluorescent perylene bisimide (F-PBI) to the CNTs was used to enhance the assembly of CNTs on the FC–water interface. The combination of different concentrations of the functionalized CNTs and the pelene additive enables predictable complex emulsion morphologies. Reversible morphology reconfiguration was explored with the addition of molecular surfactants. Our results show that the interfacial properties of functionalized CNTs have considerable utility in the fabrication of complex dynamic emulsions.
000132108 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000132108 590__ $$a4.331$$b2021
000132108 591__ $$aCHEMISTRY, PHYSICAL$$b74 / 165 = 0.448$$c2021$$dQ2$$eT2
000132108 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b72 / 179 = 0.402$$c2021$$dQ2$$eT2
000132108 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b138 / 344 = 0.401$$c2021$$dQ2$$eT2
000132108 592__ $$a0.884$$b2021
000132108 593__ $$aCondensed Matter Physics$$c2021$$dQ1
000132108 593__ $$aElectrochemistry$$c2021$$dQ1
000132108 593__ $$aSurfaces and Interfaces$$c2021$$dQ1
000132108 593__ $$aSpectroscopy$$c2021$$dQ1
000132108 593__ $$aMaterials Science (miscellaneous)$$c2021$$dQ1
000132108 594__ $$a6.7$$b2021
000132108 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000132108 700__ $$aHe, Maggie
000132108 700__ $$0(orcid)0000-0002-8932-9085$$aConcellón, Alberto
000132108 700__ $$aYoshinaga, Kosuke
000132108 700__ $$aLuo, Shao-Xiong Lennon
000132108 700__ $$aAljabri, Nouf
000132108 700__ $$aSwager, Timothy M.
000132108 773__ $$g37, 27 (2021), 8204-8211$$pLangmuir$$tLangmuir$$x0743-7463
000132108 8564_ $$s1672227$$uhttps://zaguan.unizar.es/record/132108/files/texto_completo.pdf$$yPostprint
000132108 8564_ $$s2838681$$uhttps://zaguan.unizar.es/record/132108/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000132108 909CO $$ooai:zaguan.unizar.es:132108$$particulos$$pdriver
000132108 951__ $$a2024-03-01-14:46:40
000132108 980__ $$aARTICLE