000132197 001__ 132197
000132197 005__ 20240301161206.0
000132197 0247_ $$2doi$$a10.1039/c4cp05225k
000132197 0248_ $$2sideral$$a89729
000132197 037__ $$aART-2015-89729
000132197 041__ $$aeng
000132197 100__ $$aMarin-Montesinos, I.
000132197 245__ $$aSelf-assembled trityl radical capsules -implications for dynamic nuclear polarization
000132197 260__ $$c2015
000132197 5060_ $$aAccess copy available to the general public$$fUnrestricted
000132197 5203_ $$aA new class of guest-induced, bi-radical self-assembled organic capsules is reported. They are formed by the inclusion of a tetramethylammonium (TMA) cation between two monomers of the stable trityl radical OX63. OX63 is extensively used in dissolution dynamic nuclear polarization (DNP) where it leads to NMR sensitivity enhancements of several orders of magnitude. The supramolecular properties of OX63 have a strong impact on its DNP properties. An especially relevant case is the polarization of choline-containing metabolites, where complex formation between choline and OX63 results in faster relaxation.
000132197 536__ $$9info:eu-repo/grantAgreement/EUR/COST-Action/TD1103$$9info:eu-repo/grantAgreement/EC/FP7/261863/EU/NMR for Structural Biology/BIO-NMR$$9info:eu-repo/grantAgreement/ES/MINECO/BIO2010-15683$$9info:eu-repo/grantAgreement/ES/MINECO/BIO2013-45793R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2012-38318-C03-01
000132197 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000132197 590__ $$a4.449$$b2015
000132197 591__ $$aPHYSICS, ATOMIC, MOLECULAR & CHEMICAL$$b6 / 35 = 0.171$$c2015$$dQ1$$eT1
000132197 591__ $$aCHEMISTRY, PHYSICAL$$b32 / 144 = 0.222$$c2015$$dQ1$$eT1
000132197 592__ $$a1.725$$b2015
000132197 593__ $$aPhysics and Astronomy (miscellaneous)$$c2015$$dQ1
000132197 593__ $$aPhysical and Theoretical Chemistry$$c2015$$dQ1
000132197 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000132197 700__ $$aPaniagua, J.C.
000132197 700__ $$aVilaseca, M.
000132197 700__ $$0(orcid)0000-0002-8424-9780$$aUrtizberea, A.
000132197 700__ $$0(orcid)0000-0001-6284-0521$$aLuis, F.$$uUniversidad de Zaragoza
000132197 700__ $$aFeliz, M.
000132197 700__ $$aLin, F.
000132197 700__ $$aVan Doorslaer, S.
000132197 700__ $$aPons, M.
000132197 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000132197 773__ $$g17, 8 (2015), 5785-5794$$pPhys. chem. chem. phys.$$tPhysical chemistry chemical physics$$x1463-9076
000132197 8564_ $$s2496234$$uhttps://zaguan.unizar.es/record/132197/files/texto_completo.pdf$$yVersión publicada
000132197 8564_ $$s2463289$$uhttps://zaguan.unizar.es/record/132197/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000132197 909CO $$ooai:zaguan.unizar.es:132197$$particulos$$pdriver
000132197 951__ $$a2024-03-01-14:51:54
000132197 980__ $$aARTICLE