000132217 001__ 132217
000132217 005__ 20251219150011.0
000132217 0247_ $$2doi$$a10.1016/j.jcat.2024.115334
000132217 0248_ $$2sideral$$a137432
000132217 037__ $$aART-2024-137432
000132217 041__ $$aeng
000132217 100__ $$aAzouzi, Karim
000132217 245__ $$aHydrogenation of carboxylic esters catalyzed by manganese catalysts supported by bidentate NHC-phosphine ligands
000132217 260__ $$c2024
000132217 5203_ $$aA series of bidentate manganese complexes with a general structure [(κ2C,P-R2PCH2CH2-NHC)Mn(CO)3Br] (NHC = N-substituted imidazolylidene) was prepared and fully characterized. These complexes were proven to be efficient catalysts for the hydrogenation of carboxylic ester derivatives with a low catalyst loading (0.5 mol%) in 2-Me-THF at 100 °C in the presence of KHBEt3. The generality of this hydrogenation was exemplified with more than 25 substrates. Experimental and computational investigations allowed to propose a rational mechanism involving an anionic tricarbonyl manganese hydride complex as the active species.
000132217 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000132217 590__ $$a6.5$$b2024
000132217 592__ $$a1.558$$b2024
000132217 591__ $$aENGINEERING, CHEMICAL$$b30 / 175 = 0.171$$c2024$$dQ1$$eT1
000132217 593__ $$aPhysical and Theoretical Chemistry$$c2024$$dQ1
000132217 591__ $$aCHEMISTRY, PHYSICAL$$b50 / 185 = 0.27$$c2024$$dQ2$$eT1
000132217 593__ $$aCatalysis$$c2024$$dQ1
000132217 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000132217 700__ $$aPointis, Romane
000132217 700__ $$aBuhaibeh, Ruqaya
000132217 700__ $$0(orcid)0000-0003-2249-6054$$aHermosilla Fernández, Pablo
000132217 700__ $$aPedussaut, Lucie
000132217 700__ $$aBoundor, Mohamed
000132217 700__ $$aBonfiglio, Anna
000132217 700__ $$aBruneau-Voisine, Antoine
000132217 700__ $$aWei, Duo
000132217 700__ $$aRoisnel, Thierry
000132217 700__ $$aDuhayon, Carine
000132217 700__ $$0(orcid)0000-0003-1707-3022$$aCasado, Miguel Ángel$$uUniversidad de Zaragoza
000132217 700__ $$aValyaev, Dmitry A.
000132217 700__ $$aCanac, Yves
000132217 700__ $$aBastin, Stéphanie
000132217 700__ $$aRaynaud, Christophe
000132217 700__ $$aSortais, Jean-Baptiste
000132217 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000132217 773__ $$g430 (2024), 115334 [10 pp.]$$pJ. catal.$$tJournal of Catalysis$$x0021-9517
000132217 8564_ $$s1749414$$uhttps://zaguan.unizar.es/record/132217/files/texto_completo.pdf$$yVersión publicada$$zinfo:eu-repo/date/embargoEnd/2026-01-27
000132217 8564_ $$s2574722$$uhttps://zaguan.unizar.es/record/132217/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada$$zinfo:eu-repo/date/embargoEnd/2026-01-27
000132217 909CO $$ooai:zaguan.unizar.es:132217$$particulos$$pdriver
000132217 951__ $$a2025-12-19-14:58:16
000132217 980__ $$aARTICLE