000132854 001__ 132854 000132854 005__ 20240315113108.0 000132854 0247_ $$2doi$$a10.1016/j.fpsl.2024.101237 000132854 0248_ $$2sideral$$a137664 000132854 037__ $$aART-2024-137664 000132854 041__ $$aeng 000132854 100__ $$0(orcid)0000-0003-2638-9221$$aCanellas, Elena$$uUniversidad de Zaragoza 000132854 245__ $$aExploring soda contamination coming from paper straws through ultra-high-pressure liquid chromatography coupled with an ion mobility-quadrupole time-of-flight analyzer and advanced statistical analysis 000132854 260__ $$c2024 000132854 5060_ $$aAccess copy available to the general public$$fUnrestricted 000132854 5203_ $$aThis study deals with the migration of compounds from printed straws into a carbonated drink (soda), employing an innovative approach that combines Ultra-High-Pressure Liquid Chromatography with Ion Mobility Quadrupole Time of Flight Mass Spectrometry technology. Nineteen compounds were found to migrate to the soda from the nine samples analyzed with concentrations ranging values from 0.015 to 3.6 mg migrant/kg of soda. Variations in the compounds across obtained from three different manufacturers were found. These differences strongly suggest the use of different additives in the production of straws from the different manufacturers. Additionally, discrepancies in the compounds that migrated from the printed straws produced by one manufacturer were identified. Two photoinitiators, 2,2-dimethoxy-2-phenylacetophenone and diphenyl (2,4,6-trimethylbenzoyl)- phosphine oxide and a dye, rhodamine B were found to migrate from the soda to the straws. Particularly interesting was the migration of bis(2-ethylbutyl)phthalate and dioctyl phthalate, both recognized as endocrine disruptors, and 4,4'-methylenedianiline, a primary aromatic amine and suspected carcinogen, which had a migration concentration into the soda surpassing the specific migration limit set by Regulation (EU) No 10/2011. The study underscores that, despite straws not being made of plastic, several concerning compounds that migrated from them were additives commonly found in plastic products. This may suggest that paper straws may not be the safest alternative to plastic straws in terms of food safety. 000132854 536__ $$9info:eu-repo/grantAgreement/ES/MCIN/RYC2021-034150-I$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-123742OB-I00 000132854 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/ 000132854 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000132854 700__ $$0(orcid)0000-0002-8765-4319$$aVera, Paula$$uUniversidad de Zaragoza 000132854 700__ $$0(orcid)0000-0003-2685-5739$$aNerin, Cristina$$uUniversidad de Zaragoza 000132854 700__ $$aGoshawk, Jeff 000132854 700__ $$aDreolin, Nicola 000132854 7102_ $$12009$$2750$$aUniversidad de Zaragoza$$bDpto. Química Analítica$$cÁrea Química Analítica 000132854 7102_ $$12009$$2X$$aUniversidad de Zaragoza$$bDpto. Química Analítica$$cProy. investigación HVA 000132854 773__ $$g41 (2024), 101237 [10 pp.]$$tFood Packaging and Shelf Life$$x2214-2894 000132854 8564_ $$s1376509$$uhttps://zaguan.unizar.es/record/132854/files/texto_completo.pdf$$yVersión publicada 000132854 8564_ $$s2500895$$uhttps://zaguan.unizar.es/record/132854/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000132854 909CO $$ooai:zaguan.unizar.es:132854$$particulos$$pdriver 000132854 951__ $$a2024-03-15-08:51:15 000132854 980__ $$aARTICLE