000133403 001__ 133403
000133403 005__ 20240412150654.0
000133403 0247_ $$2doi$$a10.1039/d3ta06648g
000133403 0248_ $$2sideral$$a138075
000133403 037__ $$aART-2024-138075
000133403 041__ $$aeng
000133403 100__ $$aKumar, Subodh
000133403 245__ $$aOn-surface magnetocaloric effect for a van der Waals Gd(iii) 2D MOF grown on Si
000133403 260__ $$c2024
000133403 5060_ $$aAccess copy available to the general public$$fUnrestricted
000133403 5203_ $$aGd complexes have been studied as magnetic coolants due to their large magneto-caloric effect. In this work we present a Gd 2D metal–organic framework (MOF) of formula [Gd(MeCOO)(PhCOO)2] (1). We characterize the magnetic properties of 1, showing that it displays slow relaxation of the magnetization by ac susceptibility, and single-ion magnetic anisotropy using high-field EPR. By heat capacity and magnetization vs. field at various temperatures we determine the magnetic entropy change of compound 1. We then grow 1 on functionalized silicon, and show that the surface-deposited 2D MOF 1Si can be used as an on-surface magnetic cryogenic coolant.
000133403 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E12-23R-RASMIA$$9info:eu-repo/grantAgreement/ES/MICINN/PGC2018-098630-B-I00$$9info:eu-repo/grantAgreement/ES/MICINN/PID2022-137764OB-I00
000133403 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000133403 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000133403 700__ $$aRiera, Guillem Gabarró
000133403 700__ $$0(orcid)0000-0002-5999-341X$$aArauzo, Ana$$uUniversidad de Zaragoza
000133403 700__ $$aHrubý, Jakub
000133403 700__ $$aHill, Stephen
000133403 700__ $$aBogani, Lapo
000133403 700__ $$aRubio-Zuazo, Juan
000133403 700__ $$aJover, Jesús
000133403 700__ $$aBartolomé, Elena
000133403 700__ $$aSañudo, E. Carolina
000133403 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000133403 773__ $$g12, 11 (2024), 6269-6279$$pJ. mater. chem. A$$tJournal of Materials Chemistry A$$x2050-7488
000133403 8564_ $$s1938300$$uhttps://zaguan.unizar.es/record/133403/files/texto_completo.pdf$$yVersión publicada
000133403 8564_ $$s2685426$$uhttps://zaguan.unizar.es/record/133403/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000133403 909CO $$ooai:zaguan.unizar.es:133403$$particulos$$pdriver
000133403 951__ $$a2024-04-12-13:59:38
000133403 980__ $$aARTICLE