133403 20260217205510.0 doi 10.1039/d3ta06648g sideral 138075 ART-2024-138075 eng Kumar, Subodh On-surface magnetocaloric effect for a van der Waals Gd(iii) 2D MOF grown on Si 2024 Access copy available to the general public Unrestricted Gd complexes have been studied as magnetic coolants due to their large magneto-caloric effect. In this work we present a Gd 2D metal–organic framework (MOF) of formula [Gd(MeCOO)(PhCOO)2] (1). We characterize the magnetic properties of 1, showing that it displays slow relaxation of the magnetization by ac susceptibility, and single-ion magnetic anisotropy using high-field EPR. By heat capacity and magnetization vs. field at various temperatures we determine the magnetic entropy change of compound 1. We then grow 1 on functionalized silicon, and show that the surface-deposited 2D MOF 1Si can be used as an on-surface magnetic cryogenic coolant. info:eu-repo/grantAgreement/ES/DGA-FSE/E12-23R-RASMIA info:eu-repo/grantAgreement/ES/MICINN/PGC2018-098630-B-I00 info:eu-repo/grantAgreement/ES/MICINN/PID2022-137764OB-I00 info:eu-repo/semantics/openAccess by-nc https://creativecommons.org/licenses/by-nc/4.0/deed.es 9.5 2024 CHEMISTRY, PHYSICAL 33 / 185 = 0.178 2024 Q1 T1 MATERIALS SCIENCE, MULTIDISCIPLINARY 63 / 461 = 0.137 2024 Q1 T1 ENERGY & FUELS 29 / 182 = 0.159 2024 Q1 T1 2.462 2024 Chemistry (miscellaneous) 2024 Q1 Renewable Energy, Sustainability and the Environment 2024 Q1 Materials Science (miscellaneous) 2024 Q1 16.7 2024 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Riera, Guillem Gabarró Arauzo, Ana Universidad de Zaragoza (orcid)0000-0002-5999-341X Hrubý, Jakub Hill, Stephen Bogani, Lapo Rubio-Zuazo, Juan Jover, Jesús Bartolomé, Elena Sañudo, E. Carolina 2003 395 Universidad de Zaragoza Dpto. Física Materia Condensa. Área Física Materia Condensada 12, 11 (2024), 6269-6279 J. mater. chem. A Journal of Materials Chemistry A 2050-7488 1938300 http://zaguan.unizar.es/record/133403/files/texto_completo.pdf Versión publicada 2685426 http://zaguan.unizar.es/record/133403/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:133403 articulos driver 2026-02-17-20:24:54 ARTICLE